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Crystal structure of (E)-3-{[2-(2,4-di­chloro­benzyl­idene)hydrazin-1-yl]carbon­yl}pyridinium chloride trihydrate

In the title hydrated salt, C(13)H(10)Cl(2)N(3)O(+)·Cl(−)·3H(2)O, the organic cation exhibits a dihedral angle of 8.26 (14)° between the mean planes of the pyridinium and benzene rings, and dihedral angles of 8.70 (15) and 15.93 (5)° between the mean planes of the hydrazide group and the benzene and...

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Detalles Bibliográficos
Autores principales: Novina, J. Josephine, Vasuki, G., Suresh, M., Padusha, M. Syed Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384619/
https://www.ncbi.nlm.nih.gov/pubmed/25878853
http://dx.doi.org/10.1107/S2056989015000286
Descripción
Sumario:In the title hydrated salt, C(13)H(10)Cl(2)N(3)O(+)·Cl(−)·3H(2)O, the organic cation exhibits a dihedral angle of 8.26 (14)° between the mean planes of the pyridinium and benzene rings, and dihedral angles of 8.70 (15) and 15.93 (5)° between the mean planes of the hydrazide group and the benzene and pyridinium rings, respectively. In the crystal, N—H⋯O, N—H⋯Cl, C—H⋯O, C—H⋯Cl, O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen bonds link the complex cations, chloride anions and solvent water mol­ecules into a three-dimensional network.