Crystal structure of (E)-3-{[2-(2,4-di­chloro­benzyl­idene)hydrazin-1-yl]carbon­yl}pyridinium chloride trihydrate

In the title hydrated salt, C(13)H(10)Cl(2)N(3)O(+)·Cl(−)·3H(2)O, the organic cation exhibits a dihedral angle of 8.26 (14)° between the mean planes of the pyridinium and benzene rings, and dihedral angles of 8.70 (15) and 15.93 (5)° between the mean planes of the hydrazide group and the benzene and...

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Autores principales: Novina, J. Josephine, Vasuki, G., Suresh, M., Padusha, M. Syed Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384619/
https://www.ncbi.nlm.nih.gov/pubmed/25878853
http://dx.doi.org/10.1107/S2056989015000286
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author Novina, J. Josephine
Vasuki, G.
Suresh, M.
Padusha, M. Syed Ali
author_facet Novina, J. Josephine
Vasuki, G.
Suresh, M.
Padusha, M. Syed Ali
author_sort Novina, J. Josephine
collection PubMed
description In the title hydrated salt, C(13)H(10)Cl(2)N(3)O(+)·Cl(−)·3H(2)O, the organic cation exhibits a dihedral angle of 8.26 (14)° between the mean planes of the pyridinium and benzene rings, and dihedral angles of 8.70 (15) and 15.93 (5)° between the mean planes of the hydrazide group and the benzene and pyridinium rings, respectively. In the crystal, N—H⋯O, N—H⋯Cl, C—H⋯O, C—H⋯Cl, O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen bonds link the complex cations, chloride anions and solvent water mol­ecules into a three-dimensional network.
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spelling pubmed-43846192015-04-15 Crystal structure of (E)-3-{[2-(2,4-di­chloro­benzyl­idene)hydrazin-1-yl]carbon­yl}pyridinium chloride trihydrate Novina, J. Josephine Vasuki, G. Suresh, M. Padusha, M. Syed Ali Acta Crystallogr E Crystallogr Commun Data Reports In the title hydrated salt, C(13)H(10)Cl(2)N(3)O(+)·Cl(−)·3H(2)O, the organic cation exhibits a dihedral angle of 8.26 (14)° between the mean planes of the pyridinium and benzene rings, and dihedral angles of 8.70 (15) and 15.93 (5)° between the mean planes of the hydrazide group and the benzene and pyridinium rings, respectively. In the crystal, N—H⋯O, N—H⋯Cl, C—H⋯O, C—H⋯Cl, O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen bonds link the complex cations, chloride anions and solvent water mol­ecules into a three-dimensional network. International Union of Crystallography 2015-01-10 /pmc/articles/PMC4384619/ /pubmed/25878853 http://dx.doi.org/10.1107/S2056989015000286 Text en © Novina et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Novina, J. Josephine
Vasuki, G.
Suresh, M.
Padusha, M. Syed Ali
Crystal structure of (E)-3-{[2-(2,4-di­chloro­benzyl­idene)hydrazin-1-yl]carbon­yl}pyridinium chloride trihydrate
title Crystal structure of (E)-3-{[2-(2,4-di­chloro­benzyl­idene)hydrazin-1-yl]carbon­yl}pyridinium chloride trihydrate
title_full Crystal structure of (E)-3-{[2-(2,4-di­chloro­benzyl­idene)hydrazin-1-yl]carbon­yl}pyridinium chloride trihydrate
title_fullStr Crystal structure of (E)-3-{[2-(2,4-di­chloro­benzyl­idene)hydrazin-1-yl]carbon­yl}pyridinium chloride trihydrate
title_full_unstemmed Crystal structure of (E)-3-{[2-(2,4-di­chloro­benzyl­idene)hydrazin-1-yl]carbon­yl}pyridinium chloride trihydrate
title_short Crystal structure of (E)-3-{[2-(2,4-di­chloro­benzyl­idene)hydrazin-1-yl]carbon­yl}pyridinium chloride trihydrate
title_sort crystal structure of (e)-3-{[2-(2,4-di­chloro­benzyl­idene)hydrazin-1-yl]carbon­yl}pyridinium chloride trihydrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384619/
https://www.ncbi.nlm.nih.gov/pubmed/25878853
http://dx.doi.org/10.1107/S2056989015000286
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AT sureshm crystalstructureofe3224dichlorobenzylidenehydrazin1ylcarbonylpyridiniumchloridetrihydrate
AT padushamsyedali crystalstructureofe3224dichlorobenzylidenehydrazin1ylcarbonylpyridiniumchloridetrihydrate

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