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Crystal structure of 4-[(E)-(4-nitrobenzylidene)amino]phenol
The asymmetric unit of the title compound, C(13)H(10)N(2)O(3), contains four independent molecules (I, II, III and IV). Molecule IV shows whole-molecule disorder over two sets of adjacent sites in a 0.669 (10):0.331 (10) ratio. The dihedral angles between the aromatic rings are 32.30 (13)° in mol...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384620/ https://www.ncbi.nlm.nih.gov/pubmed/25878858 http://dx.doi.org/10.1107/S2056989015000511 |
Sumario: | The asymmetric unit of the title compound, C(13)H(10)N(2)O(3), contains four independent molecules (I, II, III and IV). Molecule IV shows whole-molecule disorder over two sets of adjacent sites in a 0.669 (10):0.331 (10) ratio. The dihedral angles between the aromatic rings are 32.30 (13)° in molecule I, 2.24 (14)° in II, 41.61 (13)° in III, 5.0 (5)° in IV (major component) and 10.2 (3)° in IV (minor component). In the crystal, molecules are linked into layers lying parallel to (024) by C—H⋯O and O—H⋯O interactions. The layers interact by C—H⋯π and weak aromatic π–π stacking interactions [centroid–centroid distances = 3.8476 (16), 3.725 (3) and 3.733 (5) Å]. |
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