Crystal structure of 4-[(E)-(4-nitro­benzyl­idene)amino]­phenol

The asymmetric unit of the title compound, C(13)H(10)N(2)O(3), contains four independent mol­ecules (I, II, III and IV). Mol­ecule IV shows whole-mol­ecule disorder over two sets of adjacent sites in a 0.669 (10):0.331 (10) ratio. The dihedral angles between the aromatic rings are 32.30 (13)° in mol...

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Autores principales: Atioğlu, Zeliha, Akkurt, Mehmet, Jarrahpour, Aliasghar, Ebrahimi, Edris, Büyükgüngör, Orhan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384620/
https://www.ncbi.nlm.nih.gov/pubmed/25878858
http://dx.doi.org/10.1107/S2056989015000511
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author Atioğlu, Zeliha
Akkurt, Mehmet
Jarrahpour, Aliasghar
Ebrahimi, Edris
Büyükgüngör, Orhan
author_facet Atioğlu, Zeliha
Akkurt, Mehmet
Jarrahpour, Aliasghar
Ebrahimi, Edris
Büyükgüngör, Orhan
author_sort Atioğlu, Zeliha
collection PubMed
description The asymmetric unit of the title compound, C(13)H(10)N(2)O(3), contains four independent mol­ecules (I, II, III and IV). Mol­ecule IV shows whole-mol­ecule disorder over two sets of adjacent sites in a 0.669 (10):0.331 (10) ratio. The dihedral angles between the aromatic rings are 32.30 (13)° in mol­ecule I, 2.24 (14)° in II, 41.61 (13)° in III, 5.0 (5)° in IV (major component) and 10.2 (3)° in IV (minor component). In the crystal, mol­ecules are linked into layers lying parallel to (024) by C—H⋯O and O—H⋯O inter­actions. The layers inter­act by C—H⋯π and weak aromatic π–π stacking inter­actions [centroid–centroid distances = 3.8476 (16), 3.725 (3) and 3.733 (5) Å].
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spelling pubmed-43846202015-04-15 Crystal structure of 4-[(E)-(4-nitro­benzyl­idene)amino]­phenol Atioğlu, Zeliha Akkurt, Mehmet Jarrahpour, Aliasghar Ebrahimi, Edris Büyükgüngör, Orhan Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title compound, C(13)H(10)N(2)O(3), contains four independent mol­ecules (I, II, III and IV). Mol­ecule IV shows whole-mol­ecule disorder over two sets of adjacent sites in a 0.669 (10):0.331 (10) ratio. The dihedral angles between the aromatic rings are 32.30 (13)° in mol­ecule I, 2.24 (14)° in II, 41.61 (13)° in III, 5.0 (5)° in IV (major component) and 10.2 (3)° in IV (minor component). In the crystal, mol­ecules are linked into layers lying parallel to (024) by C—H⋯O and O—H⋯O inter­actions. The layers inter­act by C—H⋯π and weak aromatic π–π stacking inter­actions [centroid–centroid distances = 3.8476 (16), 3.725 (3) and 3.733 (5) Å]. International Union of Crystallography 2015-01-17 /pmc/articles/PMC4384620/ /pubmed/25878858 http://dx.doi.org/10.1107/S2056989015000511 Text en © Atioğlu et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Atioğlu, Zeliha
Akkurt, Mehmet
Jarrahpour, Aliasghar
Ebrahimi, Edris
Büyükgüngör, Orhan
Crystal structure of 4-[(E)-(4-nitro­benzyl­idene)amino]­phenol
title Crystal structure of 4-[(E)-(4-nitro­benzyl­idene)amino]­phenol
title_full Crystal structure of 4-[(E)-(4-nitro­benzyl­idene)amino]­phenol
title_fullStr Crystal structure of 4-[(E)-(4-nitro­benzyl­idene)amino]­phenol
title_full_unstemmed Crystal structure of 4-[(E)-(4-nitro­benzyl­idene)amino]­phenol
title_short Crystal structure of 4-[(E)-(4-nitro­benzyl­idene)amino]­phenol
title_sort crystal structure of 4-[(e)-(4-nitro­benzyl­idene)amino]­phenol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384620/
https://www.ncbi.nlm.nih.gov/pubmed/25878858
http://dx.doi.org/10.1107/S2056989015000511
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