Crystal structure of 4-[1-(2-hy­droxy­prop­yl)-4,5-diphenyl-1H-imidazol-2-yl]benzoic acid

In the title compound, C(25)H(22)N(2)O(3), the central imidazole ring makes dihedral angles of 48.43 (10), 20.23 (10) and 75.38 (11)° with the benzene ring and the two phenyl rings, respectively. The phenyl ring adjacent to the N-bonded 2-hy­droxy­propyl group shows the greatest twist, presumably to...

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Autores principales: Jasinski, Jerry P., Mohamed, Shaaban K., Akkurt, Mehmet, Abdelhamid, Antar A., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384621/
https://www.ncbi.nlm.nih.gov/pubmed/25878880
http://dx.doi.org/10.1107/S2056989014027078
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author Jasinski, Jerry P.
Mohamed, Shaaban K.
Akkurt, Mehmet
Abdelhamid, Antar A.
Albayati, Mustafa R.
author_facet Jasinski, Jerry P.
Mohamed, Shaaban K.
Akkurt, Mehmet
Abdelhamid, Antar A.
Albayati, Mustafa R.
author_sort Jasinski, Jerry P.
collection PubMed
description In the title compound, C(25)H(22)N(2)O(3), the central imidazole ring makes dihedral angles of 48.43 (10), 20.23 (10) and 75.38 (11)° with the benzene ring and the two phenyl rings, respectively. The phenyl ring adjacent to the N-bonded 2-hy­droxy­propyl group shows the greatest twist, presumably to minimize steric inter­actions. In the crystal, mol­ecules are linked by O—H⋯N, O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network. In addition, C—H⋯π inter­actions are also observed.
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spelling pubmed-43846212015-04-15 Crystal structure of 4-[1-(2-hy­droxy­prop­yl)-4,5-diphenyl-1H-imidazol-2-yl]benzoic acid Jasinski, Jerry P. Mohamed, Shaaban K. Akkurt, Mehmet Abdelhamid, Antar A. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(25)H(22)N(2)O(3), the central imidazole ring makes dihedral angles of 48.43 (10), 20.23 (10) and 75.38 (11)° with the benzene ring and the two phenyl rings, respectively. The phenyl ring adjacent to the N-bonded 2-hy­droxy­propyl group shows the greatest twist, presumably to minimize steric inter­actions. In the crystal, mol­ecules are linked by O—H⋯N, O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network. In addition, C—H⋯π inter­actions are also observed. International Union of Crystallography 2015-01-03 /pmc/articles/PMC4384621/ /pubmed/25878880 http://dx.doi.org/10.1107/S2056989014027078 Text en © Jasinski et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Jasinski, Jerry P.
Mohamed, Shaaban K.
Akkurt, Mehmet
Abdelhamid, Antar A.
Albayati, Mustafa R.
Crystal structure of 4-[1-(2-hy­droxy­prop­yl)-4,5-diphenyl-1H-imidazol-2-yl]benzoic acid
title Crystal structure of 4-[1-(2-hy­droxy­prop­yl)-4,5-diphenyl-1H-imidazol-2-yl]benzoic acid
title_full Crystal structure of 4-[1-(2-hy­droxy­prop­yl)-4,5-diphenyl-1H-imidazol-2-yl]benzoic acid
title_fullStr Crystal structure of 4-[1-(2-hy­droxy­prop­yl)-4,5-diphenyl-1H-imidazol-2-yl]benzoic acid
title_full_unstemmed Crystal structure of 4-[1-(2-hy­droxy­prop­yl)-4,5-diphenyl-1H-imidazol-2-yl]benzoic acid
title_short Crystal structure of 4-[1-(2-hy­droxy­prop­yl)-4,5-diphenyl-1H-imidazol-2-yl]benzoic acid
title_sort crystal structure of 4-[1-(2-hy­droxy­prop­yl)-4,5-diphenyl-1h-imidazol-2-yl]benzoic acid
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384621/
https://www.ncbi.nlm.nih.gov/pubmed/25878880
http://dx.doi.org/10.1107/S2056989014027078
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