Crystal structure of (pyridine-κN)bis(quinolin-2-olato-κ(2) N,O)copper(II) monohydrate

The title complex, [Cu(C(9)H(6)NO)(2)(C(5)H(4)N)]·H(2)O, adopts a slightly distorted square-pyramidal geometry in which the axial pyridine ligand exhibits a long Cu—N bond of 2.305 (3) Å. The pyridine ligand forms dihedral angles of 79.5 (5) and 88.0 (1)° with the planes of the two quinolin-2-olate...

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Detalles Bibliográficos
Autores principales: Hawks, Benjamin, Yan, Jingjing, Basa, Prem, Burdette, Shawn
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384625/
https://www.ncbi.nlm.nih.gov/pubmed/25878845
http://dx.doi.org/10.1107/S2056989015001279
Descripción
Sumario:The title complex, [Cu(C(9)H(6)NO)(2)(C(5)H(4)N)]·H(2)O, adopts a slightly distorted square-pyramidal geometry in which the axial pyridine ligand exhibits a long Cu—N bond of 2.305 (3) Å. The pyridine ligand forms dihedral angles of 79.5 (5) and 88.0 (1)° with the planes of the two quinolin-2-olate ligands, while the dihedral angle between the quinoline groups of 9.0 (3)° indicates near planarity. The water mol­ecule connects adjacent copper complexes through O—H⋯O hydrogen bonds to phenolate O atoms, forming a network inter­connecting all the complexes in the crystal lattice.

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