Crystal structure of (pyridine-κN)bis(quinolin-2-olato-κ(2) N,O)copper(II) monohydrate

The title complex, [Cu(C(9)H(6)NO)(2)(C(5)H(4)N)]·H(2)O, adopts a slightly distorted square-pyramidal geometry in which the axial pyridine ligand exhibits a long Cu—N bond of 2.305 (3) Å. The pyridine ligand forms dihedral angles of 79.5 (5) and 88.0 (1)° with the planes of the two quinolin-2-olate...

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Detalles Bibliográficos
Autores principales: Hawks, Benjamin, Yan, Jingjing, Basa, Prem, Burdette, Shawn
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384625/
https://www.ncbi.nlm.nih.gov/pubmed/25878845
http://dx.doi.org/10.1107/S2056989015001279
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author Hawks, Benjamin
Yan, Jingjing
Basa, Prem
Burdette, Shawn
author_facet Hawks, Benjamin
Yan, Jingjing
Basa, Prem
Burdette, Shawn
author_sort Hawks, Benjamin
collection PubMed
description The title complex, [Cu(C(9)H(6)NO)(2)(C(5)H(4)N)]·H(2)O, adopts a slightly distorted square-pyramidal geometry in which the axial pyridine ligand exhibits a long Cu—N bond of 2.305 (3) Å. The pyridine ligand forms dihedral angles of 79.5 (5) and 88.0 (1)° with the planes of the two quinolin-2-olate ligands, while the dihedral angle between the quinoline groups of 9.0 (3)° indicates near planarity. The water mol­ecule connects adjacent copper complexes through O—H⋯O hydrogen bonds to phenolate O atoms, forming a network inter­connecting all the complexes in the crystal lattice.
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spelling pubmed-43846252015-04-15 Crystal structure of (pyridine-κN)bis(quinolin-2-olato-κ(2) N,O)copper(II) monohydrate Hawks, Benjamin Yan, Jingjing Basa, Prem Burdette, Shawn Acta Crystallogr E Crystallogr Commun Data Reports The title complex, [Cu(C(9)H(6)NO)(2)(C(5)H(4)N)]·H(2)O, adopts a slightly distorted square-pyramidal geometry in which the axial pyridine ligand exhibits a long Cu—N bond of 2.305 (3) Å. The pyridine ligand forms dihedral angles of 79.5 (5) and 88.0 (1)° with the planes of the two quinolin-2-olate ligands, while the dihedral angle between the quinoline groups of 9.0 (3)° indicates near planarity. The water mol­ecule connects adjacent copper complexes through O—H⋯O hydrogen bonds to phenolate O atoms, forming a network inter­connecting all the complexes in the crystal lattice. International Union of Crystallography 2015-01-28 /pmc/articles/PMC4384625/ /pubmed/25878845 http://dx.doi.org/10.1107/S2056989015001279 Text en © Hawks et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Hawks, Benjamin
Yan, Jingjing
Basa, Prem
Burdette, Shawn
Crystal structure of (pyridine-κN)bis(quinolin-2-olato-κ(2) N,O)copper(II) monohydrate
title Crystal structure of (pyridine-κN)bis(quinolin-2-olato-κ(2) N,O)copper(II) monohydrate
title_full Crystal structure of (pyridine-κN)bis(quinolin-2-olato-κ(2) N,O)copper(II) monohydrate
title_fullStr Crystal structure of (pyridine-κN)bis(quinolin-2-olato-κ(2) N,O)copper(II) monohydrate
title_full_unstemmed Crystal structure of (pyridine-κN)bis(quinolin-2-olato-κ(2) N,O)copper(II) monohydrate
title_short Crystal structure of (pyridine-κN)bis(quinolin-2-olato-κ(2) N,O)copper(II) monohydrate
title_sort crystal structure of (pyridine-κn)bis(quinolin-2-olato-κ(2) n,o)copper(ii) monohydrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384625/
https://www.ncbi.nlm.nih.gov/pubmed/25878845
http://dx.doi.org/10.1107/S2056989015001279
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