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Crystal structure of 2-benzyl­amino-4-p-tolyl-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile

The title compound, C(23)H(21)N(3), comprises a 2-amino-3-cyano­pyridine ring fused with a cyclo­pentane ring. The later adopts an envelope conformation with the central methyl­ene C atom as the flap. The benzyl and and p-tolyl rings are inclined to one another by 56.18 (15)°, and to the pyridine ri...

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Detalles Bibliográficos
Autores principales: Nagalakshmi, R. A., Suresh, J., Maharani, S., Kumar, R. Ranjith, Lakshman, P. L. Nilantha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384633/
https://www.ncbi.nlm.nih.gov/pubmed/25878816
http://dx.doi.org/10.1107/S2056989015000572
Descripción
Sumario:The title compound, C(23)H(21)N(3), comprises a 2-amino-3-cyano­pyridine ring fused with a cyclo­pentane ring. The later adopts an envelope conformation with the central methyl­ene C atom as the flap. The benzyl and and p-tolyl rings are inclined to one another by 56.18 (15)°, and to the pyridine ring by 81.87 (14) and 47.60 (11)°, respectively. In the crystal, mol­ecules are linked by pairs of N—H⋯N(nitrile) hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are linked by C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.7211 (12) Å], forming a three-dimensional framework.