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Crystal structure of 2-benzyl­amino-4-p-tolyl-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile

The title compound, C(23)H(21)N(3), comprises a 2-amino-3-cyano­pyridine ring fused with a cyclo­pentane ring. The later adopts an envelope conformation with the central methyl­ene C atom as the flap. The benzyl and and p-tolyl rings are inclined to one another by 56.18 (15)°, and to the pyridine ri...

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Autores principales: Nagalakshmi, R. A., Suresh, J., Maharani, S., Kumar, R. Ranjith, Lakshman, P. L. Nilantha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384633/
https://www.ncbi.nlm.nih.gov/pubmed/25878816
http://dx.doi.org/10.1107/S2056989015000572
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author Nagalakshmi, R. A.
Suresh, J.
Maharani, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
author_facet Nagalakshmi, R. A.
Suresh, J.
Maharani, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
author_sort Nagalakshmi, R. A.
collection PubMed
description The title compound, C(23)H(21)N(3), comprises a 2-amino-3-cyano­pyridine ring fused with a cyclo­pentane ring. The later adopts an envelope conformation with the central methyl­ene C atom as the flap. The benzyl and and p-tolyl rings are inclined to one another by 56.18 (15)°, and to the pyridine ring by 81.87 (14) and 47.60 (11)°, respectively. In the crystal, mol­ecules are linked by pairs of N—H⋯N(nitrile) hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are linked by C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.7211 (12) Å], forming a three-dimensional framework.
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spelling pubmed-43846332015-04-15 Crystal structure of 2-benzyl­amino-4-p-tolyl-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile Nagalakshmi, R. A. Suresh, J. Maharani, S. Kumar, R. Ranjith Lakshman, P. L. Nilantha Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(23)H(21)N(3), comprises a 2-amino-3-cyano­pyridine ring fused with a cyclo­pentane ring. The later adopts an envelope conformation with the central methyl­ene C atom as the flap. The benzyl and and p-tolyl rings are inclined to one another by 56.18 (15)°, and to the pyridine ring by 81.87 (14) and 47.60 (11)°, respectively. In the crystal, mol­ecules are linked by pairs of N—H⋯N(nitrile) hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are linked by C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.7211 (12) Å], forming a three-dimensional framework. International Union of Crystallography 2015-01-21 /pmc/articles/PMC4384633/ /pubmed/25878816 http://dx.doi.org/10.1107/S2056989015000572 Text en © Nagalakshmi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Nagalakshmi, R. A.
Suresh, J.
Maharani, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
Crystal structure of 2-benzyl­amino-4-p-tolyl-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile
title Crystal structure of 2-benzyl­amino-4-p-tolyl-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile
title_full Crystal structure of 2-benzyl­amino-4-p-tolyl-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile
title_fullStr Crystal structure of 2-benzyl­amino-4-p-tolyl-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile
title_full_unstemmed Crystal structure of 2-benzyl­amino-4-p-tolyl-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile
title_short Crystal structure of 2-benzyl­amino-4-p-tolyl-6,7-di­hydro-5H-cyclo­penta­[b]pyridine-3-carbo­nitrile
title_sort crystal structure of 2-benzyl­amino-4-p-tolyl-6,7-di­hydro-5h-cyclo­penta­[b]pyridine-3-carbo­nitrile
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384633/
https://www.ncbi.nlm.nih.gov/pubmed/25878816
http://dx.doi.org/10.1107/S2056989015000572
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