Cargando…
Crystal structure of 2-benzylamino-4-p-tolyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile
The title compound, C(23)H(21)N(3), comprises a 2-amino-3-cyanopyridine ring fused with a cyclopentane ring. The later adopts an envelope conformation with the central methylene C atom as the flap. The benzyl and and p-tolyl rings are inclined to one another by 56.18 (15)°, and to the pyridine ri...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384633/ https://www.ncbi.nlm.nih.gov/pubmed/25878816 http://dx.doi.org/10.1107/S2056989015000572 |
_version_ | 1782364936773566464 |
---|---|
author | Nagalakshmi, R. A. Suresh, J. Maharani, S. Kumar, R. Ranjith Lakshman, P. L. Nilantha |
author_facet | Nagalakshmi, R. A. Suresh, J. Maharani, S. Kumar, R. Ranjith Lakshman, P. L. Nilantha |
author_sort | Nagalakshmi, R. A. |
collection | PubMed |
description | The title compound, C(23)H(21)N(3), comprises a 2-amino-3-cyanopyridine ring fused with a cyclopentane ring. The later adopts an envelope conformation with the central methylene C atom as the flap. The benzyl and and p-tolyl rings are inclined to one another by 56.18 (15)°, and to the pyridine ring by 81.87 (14) and 47.60 (11)°, respectively. In the crystal, molecules are linked by pairs of N—H⋯N(nitrile) hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are linked by C—H⋯π and π–π interactions [centroid–centroid distance = 3.7211 (12) Å], forming a three-dimensional framework. |
format | Online Article Text |
id | pubmed-4384633 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43846332015-04-15 Crystal structure of 2-benzylamino-4-p-tolyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile Nagalakshmi, R. A. Suresh, J. Maharani, S. Kumar, R. Ranjith Lakshman, P. L. Nilantha Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(23)H(21)N(3), comprises a 2-amino-3-cyanopyridine ring fused with a cyclopentane ring. The later adopts an envelope conformation with the central methylene C atom as the flap. The benzyl and and p-tolyl rings are inclined to one another by 56.18 (15)°, and to the pyridine ring by 81.87 (14) and 47.60 (11)°, respectively. In the crystal, molecules are linked by pairs of N—H⋯N(nitrile) hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are linked by C—H⋯π and π–π interactions [centroid–centroid distance = 3.7211 (12) Å], forming a three-dimensional framework. International Union of Crystallography 2015-01-21 /pmc/articles/PMC4384633/ /pubmed/25878816 http://dx.doi.org/10.1107/S2056989015000572 Text en © Nagalakshmi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Nagalakshmi, R. A. Suresh, J. Maharani, S. Kumar, R. Ranjith Lakshman, P. L. Nilantha Crystal structure of 2-benzylamino-4-p-tolyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile |
title | Crystal structure of 2-benzylamino-4-p-tolyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile |
title_full | Crystal structure of 2-benzylamino-4-p-tolyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile |
title_fullStr | Crystal structure of 2-benzylamino-4-p-tolyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile |
title_full_unstemmed | Crystal structure of 2-benzylamino-4-p-tolyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile |
title_short | Crystal structure of 2-benzylamino-4-p-tolyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile |
title_sort | crystal structure of 2-benzylamino-4-p-tolyl-6,7-dihydro-5h-cyclopenta[b]pyridine-3-carbonitrile |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384633/ https://www.ncbi.nlm.nih.gov/pubmed/25878816 http://dx.doi.org/10.1107/S2056989015000572 |
work_keys_str_mv | AT nagalakshmira crystalstructureof2benzylamino4ptolyl67dihydro5hcyclopentabpyridine3carbonitrile AT sureshj crystalstructureof2benzylamino4ptolyl67dihydro5hcyclopentabpyridine3carbonitrile AT maharanis crystalstructureof2benzylamino4ptolyl67dihydro5hcyclopentabpyridine3carbonitrile AT kumarrranjith crystalstructureof2benzylamino4ptolyl67dihydro5hcyclopentabpyridine3carbonitrile AT lakshmanplnilantha crystalstructureof2benzylamino4ptolyl67dihydro5hcyclopentabpyridine3carbonitrile |