Ion-Size-Dependent Formation of Mixed Titanium/Lanthanide Oxo Clusters

The mixed-metal oxo clusters LnTi(4)O(3)(OiPr)(2)(OMc)(11) (Ln = La, Ce; OMc = methacrylate), Ln(2)Ti(6)O(6)(OMc)(18)(HOiPr) (Ln = La, Ce, Nd, Sm) and Ln(2)Ti(4)O(4)(OMc)(14)(HOMc)(2) (Ln = Sm, Eu, Gd, Ho) have been synthesized from titanium isopropoxide, the corresponding lanthanide acetate and met...

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Autores principales: Artner, Christine, Kronister, Stefan, Czakler, Matthias, Schubert, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384754/
https://www.ncbi.nlm.nih.gov/pubmed/25866471
http://dx.doi.org/10.1002/ejic.201402670
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author Artner, Christine
Kronister, Stefan
Czakler, Matthias
Schubert, Ulrich
author_facet Artner, Christine
Kronister, Stefan
Czakler, Matthias
Schubert, Ulrich
author_sort Artner, Christine
collection PubMed
description The mixed-metal oxo clusters LnTi(4)O(3)(OiPr)(2)(OMc)(11) (Ln = La, Ce; OMc = methacrylate), Ln(2)Ti(6)O(6)(OMc)(18)(HOiPr) (Ln = La, Ce, Nd, Sm) and Ln(2)Ti(4)O(4)(OMc)(14)(HOMc)(2) (Ln = Sm, Eu, Gd, Ho) have been synthesized from titanium isopropoxide, the corresponding lanthanide acetate and methacrylic acid. The type of cluster obtained strongly depends on the size of the lanthanide ion.
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spelling pubmed-43847542015-04-09 Ion-Size-Dependent Formation of Mixed Titanium/Lanthanide Oxo Clusters Artner, Christine Kronister, Stefan Czakler, Matthias Schubert, Ulrich Eur J Inorg Chem Full Papers The mixed-metal oxo clusters LnTi(4)O(3)(OiPr)(2)(OMc)(11) (Ln = La, Ce; OMc = methacrylate), Ln(2)Ti(6)O(6)(OMc)(18)(HOiPr) (Ln = La, Ce, Nd, Sm) and Ln(2)Ti(4)O(4)(OMc)(14)(HOMc)(2) (Ln = Sm, Eu, Gd, Ho) have been synthesized from titanium isopropoxide, the corresponding lanthanide acetate and methacrylic acid. The type of cluster obtained strongly depends on the size of the lanthanide ion. WILEY-VCH Verlag 2014-11 2014-10-06 /pmc/articles/PMC4384754/ /pubmed/25866471 http://dx.doi.org/10.1002/ejic.201402670 Text en © 2014 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA. http://creativecommons.org/licenses/by-nc-nd/3.0/ This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Full Papers
Artner, Christine
Kronister, Stefan
Czakler, Matthias
Schubert, Ulrich
Ion-Size-Dependent Formation of Mixed Titanium/Lanthanide Oxo Clusters
title Ion-Size-Dependent Formation of Mixed Titanium/Lanthanide Oxo Clusters
title_full Ion-Size-Dependent Formation of Mixed Titanium/Lanthanide Oxo Clusters
title_fullStr Ion-Size-Dependent Formation of Mixed Titanium/Lanthanide Oxo Clusters
title_full_unstemmed Ion-Size-Dependent Formation of Mixed Titanium/Lanthanide Oxo Clusters
title_short Ion-Size-Dependent Formation of Mixed Titanium/Lanthanide Oxo Clusters
title_sort ion-size-dependent formation of mixed titanium/lanthanide oxo clusters
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384754/
https://www.ncbi.nlm.nih.gov/pubmed/25866471
http://dx.doi.org/10.1002/ejic.201402670
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AT czaklermatthias ionsizedependentformationofmixedtitaniumlanthanideoxoclusters
AT schubertulrich ionsizedependentformationofmixedtitaniumlanthanideoxoclusters

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