The phase transformation of CuInS(2) from chalcopyrite to wurtzite

In the present work, CuInS(2) nanoparticles have been successfully synthesized by water-bath method with deionized water as solvent and thioglycolic acid as complexing agent at 80°C. The phase transition of CuInS(2) from chalcopyrite to wurtzite was realized by adjusting the pH value of reaction sol...

Descripción completa

Detalles Bibliográficos
Autores principales: Xie, Bing-Bing, Hu, Bin-Bin, Jiang, Li-Fang, Li, Guo, Du, Zu-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2015
Materias:
Nano Express
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4385122/
https://www.ncbi.nlm.nih.gov/pubmed/25852382
http://dx.doi.org/10.1186/s11671-015-0800-z
_version_ 1782365009050861568
author Xie, Bing-Bing
Hu, Bin-Bin
Jiang, Li-Fang
Li, Guo
Du, Zu-Liang
author_facet Xie, Bing-Bing
Hu, Bin-Bin
Jiang, Li-Fang
Li, Guo
Du, Zu-Liang
author_sort Xie, Bing-Bing
collection PubMed
description In the present work, CuInS(2) nanoparticles have been successfully synthesized by water-bath method with deionized water as solvent and thioglycolic acid as complexing agent at 80°C. The phase transition of CuInS(2) from chalcopyrite to wurtzite was realized by adjusting the pH value of reaction solution. The emergence of Cu(2)S in the condition of higher pH value of reaction solution led to the formation of wurtzite CuInS(2). This facile method that controls the phase structure by adjusting the solution pH value could open a new way to synthesize other I-III-VI(2) ternary semiconductor compounds. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1186/s11671-015-0800-z) contains supplementary material, which is available to authorized users.
format Online
Article
Text
id pubmed-4385122
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher Springer US
record_format MEDLINE/PubMed
spelling pubmed-43851222015-04-07 The phase transformation of CuInS(2) from chalcopyrite to wurtzite Xie, Bing-Bing Hu, Bin-Bin Jiang, Li-Fang Li, Guo Du, Zu-Liang Nanoscale Res Lett Nano Express In the present work, CuInS(2) nanoparticles have been successfully synthesized by water-bath method with deionized water as solvent and thioglycolic acid as complexing agent at 80°C. The phase transition of CuInS(2) from chalcopyrite to wurtzite was realized by adjusting the pH value of reaction solution. The emergence of Cu(2)S in the condition of higher pH value of reaction solution led to the formation of wurtzite CuInS(2). This facile method that controls the phase structure by adjusting the solution pH value could open a new way to synthesize other I-III-VI(2) ternary semiconductor compounds. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1186/s11671-015-0800-z) contains supplementary material, which is available to authorized users. Springer US 2015-02-27 /pmc/articles/PMC4385122/ /pubmed/25852382 http://dx.doi.org/10.1186/s11671-015-0800-z Text en © Xie et al.; 2015 licensee Springer. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly credited.
spellingShingle Nano Express
Xie, Bing-Bing
Hu, Bin-Bin
Jiang, Li-Fang
Li, Guo
Du, Zu-Liang
The phase transformation of CuInS(2) from chalcopyrite to wurtzite
title The phase transformation of CuInS(2) from chalcopyrite to wurtzite
title_full The phase transformation of CuInS(2) from chalcopyrite to wurtzite
title_fullStr The phase transformation of CuInS(2) from chalcopyrite to wurtzite
title_full_unstemmed The phase transformation of CuInS(2) from chalcopyrite to wurtzite
title_short The phase transformation of CuInS(2) from chalcopyrite to wurtzite
title_sort phase transformation of cuins(2) from chalcopyrite to wurtzite
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4385122/
https://www.ncbi.nlm.nih.gov/pubmed/25852382
http://dx.doi.org/10.1186/s11671-015-0800-z
work_keys_str_mv AT xiebingbing thephasetransformationofcuins2fromchalcopyritetowurtzite
AT hubinbin thephasetransformationofcuins2fromchalcopyritetowurtzite
AT jianglifang thephasetransformationofcuins2fromchalcopyritetowurtzite
AT liguo thephasetransformationofcuins2fromchalcopyritetowurtzite
AT duzuliang thephasetransformationofcuins2fromchalcopyritetowurtzite
AT xiebingbing phasetransformationofcuins2fromchalcopyritetowurtzite
AT hubinbin phasetransformationofcuins2fromchalcopyritetowurtzite
AT jianglifang phasetransformationofcuins2fromchalcopyritetowurtzite
AT liguo phasetransformationofcuins2fromchalcopyritetowurtzite
AT duzuliang phasetransformationofcuins2fromchalcopyritetowurtzite

Ejemplares similares