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Vanadia supported on nickel manganese oxide nanocatalysts for the catalytic oxidation of aromatic alcohols

Vanadia nanoparticles supported on nickel manganese mixed oxides were synthesized by co-precipitation method. The catalytic properties of these materials were investigated for the oxidation of benzyl alcohol using molecular oxygen as oxidant. It was observed that the calcination temperature and the...

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Detalles Bibliográficos
Autores principales: Adil, Syed F, Alabbad, Saad, Kuniyil, Mufsir, Khan, Mujeeb, Alwarthan, Abdulrahman, Mohri, Nils, Tremel, Wolfgang, Tahir, Muhammad Nawaz, Siddiqui, Mohammed Rafiq Hussain
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4385214/
https://www.ncbi.nlm.nih.gov/pubmed/25852349
http://dx.doi.org/10.1186/s11671-015-0750-5
Descripción
Sumario:Vanadia nanoparticles supported on nickel manganese mixed oxides were synthesized by co-precipitation method. The catalytic properties of these materials were investigated for the oxidation of benzyl alcohol using molecular oxygen as oxidant. It was observed that the calcination temperature and the size of particles play an important role in the catalytic process. The catalyst was evaluated for its oxidation property against aliphatic and aromatic alcohols, which was found to display selectivity towards aromatic alcohols. The samples were characterized by employing scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Brunauer-Emmett-Teller analysis, thermogravimetric analysis, and X-ray photoelectron spectroscopy.