Open-Shell Lanthanide(II+) or -(III+) Complexes Bearing σ-Silyl and Silylene Ligands: Synthesis, Structure, and Bonding Analysis

[Image: see text] Complexes featuring lanthanide (Ln)–Si bonds represent a highly neglected research area. Herein, we report a series of open-shell Ln(II+) and Ln(III+) complexes bearing σ-bonded silyl and base-stabilized N-heterocyclic silylene (NHSi) ligands. The reactions of the Ln(III+) complexe...

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Detalles Bibliográficos
Autores principales: Zitz, Rainer, Arp, Henning, Hlina, Johann, Walewska, Małgorzata, Marschner, Christoph, Szilvási, Tibor, Blom, Burgert, Baumgartner, Judith
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4389698/
https://www.ncbi.nlm.nih.gov/pubmed/25756230
http://dx.doi.org/10.1021/ic502991p

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