Cargando…

Graphene-enhanced Raman spectroscopy of thymine adsorbed on single-layer graphene

Graphene-enhanced Raman scattering (GERS) spectra and coherent anti-Stokes Raman scattering (CARS) of thymine molecules adsorbed on a single-layer graphene were studied. The enhancement factor was shown to depend on the molecular groups of thymine. In the GERS spectra of thymine, the main bands are...

Descripción completa

Detalles Bibliográficos
Autores principales: Fesenko, Olena, Dovbeshko, Galyna, Dementjev, Andrej, Karpicz, Renata, Kaplas, Tommi, Svirko, Yuri
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4398685/
https://www.ncbi.nlm.nih.gov/pubmed/25897307
http://dx.doi.org/10.1186/s11671-015-0869-4
_version_ 1782366849238827008
author Fesenko, Olena
Dovbeshko, Galyna
Dementjev, Andrej
Karpicz, Renata
Kaplas, Tommi
Svirko, Yuri
author_facet Fesenko, Olena
Dovbeshko, Galyna
Dementjev, Andrej
Karpicz, Renata
Kaplas, Tommi
Svirko, Yuri
author_sort Fesenko, Olena
collection PubMed
description Graphene-enhanced Raman scattering (GERS) spectra and coherent anti-Stokes Raman scattering (CARS) of thymine molecules adsorbed on a single-layer graphene were studied. The enhancement factor was shown to depend on the molecular groups of thymine. In the GERS spectra of thymine, the main bands are shifted with respect to those for molecules adsorbed on a glass surface, indicating charge transfer for thymine on graphene. The probable mechanism of the GERS enhancement is discussed. CARS spectra are in accord with the GERS results, which indicates similar benefit from the chemical enhancement.
format Online
Article
Text
id pubmed-4398685
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher Springer US
record_format MEDLINE/PubMed
spelling pubmed-43986852015-04-20 Graphene-enhanced Raman spectroscopy of thymine adsorbed on single-layer graphene Fesenko, Olena Dovbeshko, Galyna Dementjev, Andrej Karpicz, Renata Kaplas, Tommi Svirko, Yuri Nanoscale Res Lett Nano Express Graphene-enhanced Raman scattering (GERS) spectra and coherent anti-Stokes Raman scattering (CARS) of thymine molecules adsorbed on a single-layer graphene were studied. The enhancement factor was shown to depend on the molecular groups of thymine. In the GERS spectra of thymine, the main bands are shifted with respect to those for molecules adsorbed on a glass surface, indicating charge transfer for thymine on graphene. The probable mechanism of the GERS enhancement is discussed. CARS spectra are in accord with the GERS results, which indicates similar benefit from the chemical enhancement. Springer US 2015-04-02 /pmc/articles/PMC4398685/ /pubmed/25897307 http://dx.doi.org/10.1186/s11671-015-0869-4 Text en © Fesenko et al.; licensee Springer. 2015 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly credited.
spellingShingle Nano Express
Fesenko, Olena
Dovbeshko, Galyna
Dementjev, Andrej
Karpicz, Renata
Kaplas, Tommi
Svirko, Yuri
Graphene-enhanced Raman spectroscopy of thymine adsorbed on single-layer graphene
title Graphene-enhanced Raman spectroscopy of thymine adsorbed on single-layer graphene
title_full Graphene-enhanced Raman spectroscopy of thymine adsorbed on single-layer graphene
title_fullStr Graphene-enhanced Raman spectroscopy of thymine adsorbed on single-layer graphene
title_full_unstemmed Graphene-enhanced Raman spectroscopy of thymine adsorbed on single-layer graphene
title_short Graphene-enhanced Raman spectroscopy of thymine adsorbed on single-layer graphene
title_sort graphene-enhanced raman spectroscopy of thymine adsorbed on single-layer graphene
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4398685/
https://www.ncbi.nlm.nih.gov/pubmed/25897307
http://dx.doi.org/10.1186/s11671-015-0869-4
work_keys_str_mv AT fesenkoolena grapheneenhancedramanspectroscopyofthymineadsorbedonsinglelayergraphene
AT dovbeshkogalyna grapheneenhancedramanspectroscopyofthymineadsorbedonsinglelayergraphene
AT dementjevandrej grapheneenhancedramanspectroscopyofthymineadsorbedonsinglelayergraphene
AT karpiczrenata grapheneenhancedramanspectroscopyofthymineadsorbedonsinglelayergraphene
AT kaplastommi grapheneenhancedramanspectroscopyofthymineadsorbedonsinglelayergraphene
AT svirkoyuri grapheneenhancedramanspectroscopyofthymineadsorbedonsinglelayergraphene