Z-Selective Olefin Synthesis via Iron-Catalyzed Reductive Coupling of Alkyl Halides with Terminal Arylalkynes

[Image: see text] Selective catalytic synthesis of Z-olefins has been challenging. Here we describe a method to produce 1,2-disubstituted olefins in high Z selectivity via reductive cross-coupling of alkyl halides with terminal arylalkynes. The method employs inexpensive and nontoxic catalyst (iron(...

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Detalles Bibliográficos
Autores principales: Cheung, Chi Wai, Zhurkin, Fedor E., Hu, Xile
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4415033/
https://www.ncbi.nlm.nih.gov/pubmed/25831473
http://dx.doi.org/10.1021/jacs.5b01784

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4415033/
https://www.ncbi.nlm.nih.gov/pubmed/25831473
http://dx.doi.org/10.1021/jacs.5b01784

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