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On the strong difference in reactivity of acyclic and cyclic diazodiketones with thioketones: experimental results and quantum-chemical interpretation

The 1,3-dipolar cycloaddition of acyclic 2-diazo-1,3-dicarbonyl compounds (DDC) and thioketones preferably occurs with Z,E-conformers and leads to the formation of transient thiocarbonyl ylides in two stages. The thermodynamically favorable further transformation of C=S ylides bearing at least one a...

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Detalles Bibliográficos
Autores principales:	Mereshchenko, Andrey S, Ivanov, Alexey V, Baranovskii, Viktor I, Mloston, Grzegorz, Rodina, Ludmila L, Nikolaev, Valerij A
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2015
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4419510/ https://www.ncbi.nlm.nih.gov/pubmed/25977725 http://dx.doi.org/10.3762/bjoc.11.57

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