Electrochemical oxidation of cholesterol

Indirect cholesterol electrochemical oxidation in the presence of various mediators leads to electrophilic addition to the double bond, oxidation at the allylic position, oxidation of the hydroxy group, or functionalization of the side chain. Recent studies have proven that direct electrochemical ox...

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Detalles Bibliográficos
Autores principales: Morzycki, Jacek W, Sobkowiak, Andrzej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4419515/
https://www.ncbi.nlm.nih.gov/pubmed/25977713
http://dx.doi.org/10.3762/bjoc.11.45
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author Morzycki, Jacek W
Sobkowiak, Andrzej
author_facet Morzycki, Jacek W
Sobkowiak, Andrzej
author_sort Morzycki, Jacek W
collection PubMed
description Indirect cholesterol electrochemical oxidation in the presence of various mediators leads to electrophilic addition to the double bond, oxidation at the allylic position, oxidation of the hydroxy group, or functionalization of the side chain. Recent studies have proven that direct electrochemical oxidation of cholesterol is also possible and affords different products depending on the reaction conditions.
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spelling pubmed-44195152015-05-14 Electrochemical oxidation of cholesterol Morzycki, Jacek W Sobkowiak, Andrzej Beilstein J Org Chem Review Indirect cholesterol electrochemical oxidation in the presence of various mediators leads to electrophilic addition to the double bond, oxidation at the allylic position, oxidation of the hydroxy group, or functionalization of the side chain. Recent studies have proven that direct electrochemical oxidation of cholesterol is also possible and affords different products depending on the reaction conditions. Beilstein-Institut 2015-03-25 /pmc/articles/PMC4419515/ /pubmed/25977713 http://dx.doi.org/10.3762/bjoc.11.45 Text en Copyright © 2015, Morzycki and Sobkowiak https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Review
Morzycki, Jacek W
Sobkowiak, Andrzej
Electrochemical oxidation of cholesterol
title Electrochemical oxidation of cholesterol
title_full Electrochemical oxidation of cholesterol
title_fullStr Electrochemical oxidation of cholesterol
title_full_unstemmed Electrochemical oxidation of cholesterol
title_short Electrochemical oxidation of cholesterol
title_sort electrochemical oxidation of cholesterol
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4419515/
https://www.ncbi.nlm.nih.gov/pubmed/25977713
http://dx.doi.org/10.3762/bjoc.11.45
work_keys_str_mv AT morzyckijacekw electrochemicaloxidationofcholesterol
AT sobkowiakandrzej electrochemicaloxidationofcholesterol

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