Synthesis and chemosensing properties of cinnoline-containing poly(arylene ethynylene)s

Novel poly(arylene ethynylene)s comprising a cinnoline core were prepared in high yields via a three-step methodology. A Richter-type cyclization of 2-ethynyl- and 2-(buta-1,3-diynyl)aryltriazenes was used for cinnoline ring formation, followed by a Sonogashira coupling for the introduction of trime...

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Detalles Bibliográficos
Autores principales: Danilkina, Natalia A, Vlasov, Petr S, Vodianik, Semen M, Kruchinin, Andrey A, Vlasov, Yuri G, Balova, Irina A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4419556/
https://www.ncbi.nlm.nih.gov/pubmed/25977711
http://dx.doi.org/10.3762/bjoc.11.43
Descripción
Sumario:Novel poly(arylene ethynylene)s comprising a cinnoline core were prepared in high yields via a three-step methodology. A Richter-type cyclization of 2-ethynyl- and 2-(buta-1,3-diynyl)aryltriazenes was used for cinnoline ring formation, followed by a Sonogashira coupling for the introduction of trimethylsilylethynyl moieties and a sila-Sonogashira coupling as the polycondensation technique. The fluorescence of the cinnoline-containing polymers in THF was highly sensitive to quenching by Pd(2+) ions.

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