Matsuda–Heck reaction with arenediazonium tosylates in water

An environmentally friendly Matsuda–Heck reaction with arenediazonium tosylates has been developed for the first time. A range of alkenes was arylated in good to quantitative yields in water. The reaction is significantly accelerated when carried out under microwave heating. The arylation of haloalk...

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Detalles Bibliográficos
Autores principales: Kutonova, Ksenia V, Trusova, Marina E, Stankevich, Andrey V, Postnikov, Pavel S, Filimonov, Victor D
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4419561/
https://www.ncbi.nlm.nih.gov/pubmed/25977709
http://dx.doi.org/10.3762/bjoc.11.41
Descripción
Sumario:An environmentally friendly Matsuda–Heck reaction with arenediazonium tosylates has been developed for the first time. A range of alkenes was arylated in good to quantitative yields in water. The reaction is significantly accelerated when carried out under microwave heating. The arylation of haloalkylacrylates with diazonium salts has been implemented for the first time.

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