Matsuda–Heck reaction with arenediazonium tosylates in water

An environmentally friendly Matsuda–Heck reaction with arenediazonium tosylates has been developed for the first time. A range of alkenes was arylated in good to quantitative yields in water. The reaction is significantly accelerated when carried out under microwave heating. The arylation of haloalk...

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Autores principales: Kutonova, Ksenia V, Trusova, Marina E, Stankevich, Andrey V, Postnikov, Pavel S, Filimonov, Victor D
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4419561/
https://www.ncbi.nlm.nih.gov/pubmed/25977709
http://dx.doi.org/10.3762/bjoc.11.41
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author Kutonova, Ksenia V
Trusova, Marina E
Stankevich, Andrey V
Postnikov, Pavel S
Filimonov, Victor D
author_facet Kutonova, Ksenia V
Trusova, Marina E
Stankevich, Andrey V
Postnikov, Pavel S
Filimonov, Victor D
author_sort Kutonova, Ksenia V
collection PubMed
description An environmentally friendly Matsuda–Heck reaction with arenediazonium tosylates has been developed for the first time. A range of alkenes was arylated in good to quantitative yields in water. The reaction is significantly accelerated when carried out under microwave heating. The arylation of haloalkylacrylates with diazonium salts has been implemented for the first time.
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spelling pubmed-44195612015-05-14 Matsuda–Heck reaction with arenediazonium tosylates in water Kutonova, Ksenia V Trusova, Marina E Stankevich, Andrey V Postnikov, Pavel S Filimonov, Victor D Beilstein J Org Chem Full Research Paper An environmentally friendly Matsuda–Heck reaction with arenediazonium tosylates has been developed for the first time. A range of alkenes was arylated in good to quantitative yields in water. The reaction is significantly accelerated when carried out under microwave heating. The arylation of haloalkylacrylates with diazonium salts has been implemented for the first time. Beilstein-Institut 2015-03-16 /pmc/articles/PMC4419561/ /pubmed/25977709 http://dx.doi.org/10.3762/bjoc.11.41 Text en Copyright © 2015, Kutonova et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Kutonova, Ksenia V
Trusova, Marina E
Stankevich, Andrey V
Postnikov, Pavel S
Filimonov, Victor D
Matsuda–Heck reaction with arenediazonium tosylates in water
title Matsuda–Heck reaction with arenediazonium tosylates in water
title_full Matsuda–Heck reaction with arenediazonium tosylates in water
title_fullStr Matsuda–Heck reaction with arenediazonium tosylates in water
title_full_unstemmed Matsuda–Heck reaction with arenediazonium tosylates in water
title_short Matsuda–Heck reaction with arenediazonium tosylates in water
title_sort matsuda–heck reaction with arenediazonium tosylates in water
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4419561/
https://www.ncbi.nlm.nih.gov/pubmed/25977709
http://dx.doi.org/10.3762/bjoc.11.41
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