Crystal structure of tricarbon­yltris(pyri­dine-κN)rhenium(I) tetra­fluorido­borate

In the title compound, [Re(C(6)H(5)N)(3)(CO)(3)]BF(4), the Re(I) ion is six-coordinated by three pyridine N atoms and three carbonyl C atoms. In each case, the carbonyl C atom lies trans to a pyridine N atom. In the crystal, the ions are linked via C—H⋯F hydrogen bonds and C—H⋯π inter­actions, formi...

Descripción completa

Detalles Bibliográficos
Autores principales: Ikotun, Adebomi A., Coogan, Micheal P., Owoseni, Abimbola A., Bhuvanesh, Nattamai, Egharevba, Gabriel O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420038/
https://www.ncbi.nlm.nih.gov/pubmed/25995887
http://dx.doi.org/10.1107/S2056989015006180
Descripción
Sumario:In the title compound, [Re(C(6)H(5)N)(3)(CO)(3)]BF(4), the Re(I) ion is six-coordinated by three pyridine N atoms and three carbonyl C atoms. In each case, the carbonyl C atom lies trans to a pyridine N atom. In the crystal, the ions are linked via C—H⋯F hydrogen bonds and C—H⋯π inter­actions, forming a three-dimensional framework. The F atoms of the BF(4) anion are disordered over two positions and gave a final refined occupancy ratio of 0.705 (11):0.295 (11).

Ejemplares similares