Crystal structure of tricarbon­yltris(pyri­dine-κN)rhenium(I) tetra­fluorido­borate

In the title compound, [Re(C(6)H(5)N)(3)(CO)(3)]BF(4), the Re(I) ion is six-coordinated by three pyridine N atoms and three carbonyl C atoms. In each case, the carbonyl C atom lies trans to a pyridine N atom. In the crystal, the ions are linked via C—H⋯F hydrogen bonds and C—H⋯π inter­actions, formi...

Descripción completa

Detalles Bibliográficos
Autores principales: Ikotun, Adebomi A., Coogan, Micheal P., Owoseni, Abimbola A., Bhuvanesh, Nattamai, Egharevba, Gabriel O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420038/
https://www.ncbi.nlm.nih.gov/pubmed/25995887
http://dx.doi.org/10.1107/S2056989015006180
_version_ 1782369655626661888
author Ikotun, Adebomi A.
Coogan, Micheal P.
Owoseni, Abimbola A.
Bhuvanesh, Nattamai
Egharevba, Gabriel O.
author_facet Ikotun, Adebomi A.
Coogan, Micheal P.
Owoseni, Abimbola A.
Bhuvanesh, Nattamai
Egharevba, Gabriel O.
author_sort Ikotun, Adebomi A.
collection PubMed
description In the title compound, [Re(C(6)H(5)N)(3)(CO)(3)]BF(4), the Re(I) ion is six-coordinated by three pyridine N atoms and three carbonyl C atoms. In each case, the carbonyl C atom lies trans to a pyridine N atom. In the crystal, the ions are linked via C—H⋯F hydrogen bonds and C—H⋯π inter­actions, forming a three-dimensional framework. The F atoms of the BF(4) anion are disordered over two positions and gave a final refined occupancy ratio of 0.705 (11):0.295 (11).
format Online
Article
Text
id pubmed-4420038
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-44200382015-05-20 Crystal structure of tricarbon­yltris(pyri­dine-κN)rhenium(I) tetra­fluorido­borate Ikotun, Adebomi A. Coogan, Micheal P. Owoseni, Abimbola A. Bhuvanesh, Nattamai Egharevba, Gabriel O. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, [Re(C(6)H(5)N)(3)(CO)(3)]BF(4), the Re(I) ion is six-coordinated by three pyridine N atoms and three carbonyl C atoms. In each case, the carbonyl C atom lies trans to a pyridine N atom. In the crystal, the ions are linked via C—H⋯F hydrogen bonds and C—H⋯π inter­actions, forming a three-dimensional framework. The F atoms of the BF(4) anion are disordered over two positions and gave a final refined occupancy ratio of 0.705 (11):0.295 (11). International Union of Crystallography 2015-04-11 /pmc/articles/PMC4420038/ /pubmed/25995887 http://dx.doi.org/10.1107/S2056989015006180 Text en © Ikotun et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ikotun, Adebomi A.
Coogan, Micheal P.
Owoseni, Abimbola A.
Bhuvanesh, Nattamai
Egharevba, Gabriel O.
Crystal structure of tricarbon­yltris(pyri­dine-κN)rhenium(I) tetra­fluorido­borate
title Crystal structure of tricarbon­yltris(pyri­dine-κN)rhenium(I) tetra­fluorido­borate
title_full Crystal structure of tricarbon­yltris(pyri­dine-κN)rhenium(I) tetra­fluorido­borate
title_fullStr Crystal structure of tricarbon­yltris(pyri­dine-κN)rhenium(I) tetra­fluorido­borate
title_full_unstemmed Crystal structure of tricarbon­yltris(pyri­dine-κN)rhenium(I) tetra­fluorido­borate
title_short Crystal structure of tricarbon­yltris(pyri­dine-κN)rhenium(I) tetra­fluorido­borate
title_sort crystal structure of tricarbon­yltris(pyri­dine-κn)rhenium(i) tetra­fluorido­borate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420038/
https://www.ncbi.nlm.nih.gov/pubmed/25995887
http://dx.doi.org/10.1107/S2056989015006180
work_keys_str_mv AT ikotunadebomia crystalstructureoftricarbonyltrispyridineknrheniumitetrafluoridoborate
AT cooganmichealp crystalstructureoftricarbonyltrispyridineknrheniumitetrafluoridoborate
AT owoseniabimbolaa crystalstructureoftricarbonyltrispyridineknrheniumitetrafluoridoborate
AT bhuvaneshnattamai crystalstructureoftricarbonyltrispyridineknrheniumitetrafluoridoborate
AT egharevbagabrielo crystalstructureoftricarbonyltrispyridineknrheniumitetrafluoridoborate

Ejemplares similares