Crystal structure of (1,3-di-tert-butyl-η(5)-cyclo­penta­dien­yl)tri­methyl­hafnium(IV)

The mol­ecule of the title organometallic hafnium(IV) com­pound, [Hf(CH(3))(3)(C(13)H(21))] or [HfMe(3)(η(5)-C(5)H(3)-1,3-(t)Bu(2))], adopts the classical three-legged piano-stool geometry for mono­cyclo­penta­dienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at th...

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Autores principales: Pérez-Redondo, Adrián, Varela-Izquierdo, Víctor, Yélamos, Carlos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420044/
https://www.ncbi.nlm.nih.gov/pubmed/25995884
http://dx.doi.org/10.1107/S205698901500585X
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author Pérez-Redondo, Adrián
Varela-Izquierdo, Víctor
Yélamos, Carlos
author_facet Pérez-Redondo, Adrián
Varela-Izquierdo, Víctor
Yélamos, Carlos
author_sort Pérez-Redondo, Adrián
collection PubMed
description The mol­ecule of the title organometallic hafnium(IV) com­pound, [Hf(CH(3))(3)(C(13)H(21))] or [HfMe(3)(η(5)-C(5)H(3)-1,3-(t)Bu(2))], adopts the classical three-legged piano-stool geometry for mono­cyclo­penta­dienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at the legs. The C atoms of the two tert-butyl group bonded to the cyclo­penta­dienyl (Cp) ring are 0.132 (5) and 0.154 (6) Å above the Cp least-squares plane. There are no significant inter­molecular inter­actions present between the mol­ecules in the crystal structure.
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spelling pubmed-44200442015-05-20 Crystal structure of (1,3-di-tert-butyl-η(5)-cyclo­penta­dien­yl)tri­methyl­hafnium(IV) Pérez-Redondo, Adrián Varela-Izquierdo, Víctor Yélamos, Carlos Acta Crystallogr E Crystallogr Commun Data Reports The mol­ecule of the title organometallic hafnium(IV) com­pound, [Hf(CH(3))(3)(C(13)H(21))] or [HfMe(3)(η(5)-C(5)H(3)-1,3-(t)Bu(2))], adopts the classical three-legged piano-stool geometry for mono­cyclo­penta­dienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at the legs. The C atoms of the two tert-butyl group bonded to the cyclo­penta­dienyl (Cp) ring are 0.132 (5) and 0.154 (6) Å above the Cp least-squares plane. There are no significant inter­molecular inter­actions present between the mol­ecules in the crystal structure. International Union of Crystallography 2015-04-02 /pmc/articles/PMC4420044/ /pubmed/25995884 http://dx.doi.org/10.1107/S205698901500585X Text en © Pérez-Redondo et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Pérez-Redondo, Adrián
Varela-Izquierdo, Víctor
Yélamos, Carlos
Crystal structure of (1,3-di-tert-butyl-η(5)-cyclo­penta­dien­yl)tri­methyl­hafnium(IV)
title Crystal structure of (1,3-di-tert-butyl-η(5)-cyclo­penta­dien­yl)tri­methyl­hafnium(IV)
title_full Crystal structure of (1,3-di-tert-butyl-η(5)-cyclo­penta­dien­yl)tri­methyl­hafnium(IV)
title_fullStr Crystal structure of (1,3-di-tert-butyl-η(5)-cyclo­penta­dien­yl)tri­methyl­hafnium(IV)
title_full_unstemmed Crystal structure of (1,3-di-tert-butyl-η(5)-cyclo­penta­dien­yl)tri­methyl­hafnium(IV)
title_short Crystal structure of (1,3-di-tert-butyl-η(5)-cyclo­penta­dien­yl)tri­methyl­hafnium(IV)
title_sort crystal structure of (1,3-di-tert-butyl-η(5)-cyclo­penta­dien­yl)tri­methyl­hafnium(iv)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420044/
https://www.ncbi.nlm.nih.gov/pubmed/25995884
http://dx.doi.org/10.1107/S205698901500585X
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