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Crystal structure of 4-hydroxy-3-methoxybenzaldehyde 4-methylthiosemicarbazone methanol monosolvate
In the title solvate, C(15)H(15)N(3)O(2)S·CH(3)OH, the thiosemicarbazone molecule is approximately planar; the maximum deviation from the mean plane is 0.4659 (14) Å and the dihedral angle between the aromatic rings is 9.83 (8)°. This conformation is supported by an intramolecular N—H⋯N hydrogen...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420048/ https://www.ncbi.nlm.nih.gov/pubmed/25995922 http://dx.doi.org/10.1107/S2056989015007227 |
Sumario: | In the title solvate, C(15)H(15)N(3)O(2)S·CH(3)OH, the thiosemicarbazone molecule is approximately planar; the maximum deviation from the mean plane is 0.4659 (14) Å and the dihedral angle between the aromatic rings is 9.83 (8)°. This conformation is supported by an intramolecular N—H⋯N hydrogen bond. In the crystal, the thiosemicarbazone molecules are linked into dimers by pairs of N—H⋯S hydrogen bonds, thereby generating R (2) (2)(8) loops. The methanol solvent molecule bonds to the thiosemicarbazone molecule through a bifurcated O—H⋯(O,O) hydrogen bond and also accepts an O—H⋯O link from the thiosemicarbazone molecule. Together, these links generate a three-dimensional network. |
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