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Crystal structure of bis(4-methoxyphenyl) malonate
The complete molecule of the title compound, C(17)H(16)O(6), is generated by crystallographic twofold symmetry, with the central methylene C atom lying on the rotation axis. The carbonyl O atom is disordered over two adjacent positions in a 0.63 (3):0.37 (3) ratio and the dihedral angle between th...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420049/ https://www.ncbi.nlm.nih.gov/pubmed/25995932 http://dx.doi.org/10.1107/S2056989015006891 |
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author | Devarajegowda, H. C. Suchetan, P. A. Sreenivasa, S. Srinivasa, H. T. Palakshamurthy, B. S. |
author_facet | Devarajegowda, H. C. Suchetan, P. A. Sreenivasa, S. Srinivasa, H. T. Palakshamurthy, B. S. |
author_sort | Devarajegowda, H. C. |
collection | PubMed |
description | The complete molecule of the title compound, C(17)H(16)O(6), is generated by crystallographic twofold symmetry, with the central methylene C atom lying on the rotation axis. The carbonyl O atom is disordered over two adjacent positions in a 0.63 (3):0.37 (3) ratio and the dihedral angle between the benzene rings in the two halves of the molecule is 79.31 (12)°. In the crystal, molecules are connected by C—H⋯O hydrogen bonds, generating (110) sheets. Very weak intrasheet C—H⋯π interactions are also observed. |
format | Online Article Text |
id | pubmed-4420049 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44200492015-05-20 Crystal structure of bis(4-methoxyphenyl) malonate Devarajegowda, H. C. Suchetan, P. A. Sreenivasa, S. Srinivasa, H. T. Palakshamurthy, B. S. Acta Crystallogr E Crystallogr Commun Data Reports The complete molecule of the title compound, C(17)H(16)O(6), is generated by crystallographic twofold symmetry, with the central methylene C atom lying on the rotation axis. The carbonyl O atom is disordered over two adjacent positions in a 0.63 (3):0.37 (3) ratio and the dihedral angle between the benzene rings in the two halves of the molecule is 79.31 (12)°. In the crystal, molecules are connected by C—H⋯O hydrogen bonds, generating (110) sheets. Very weak intrasheet C—H⋯π interactions are also observed. International Union of Crystallography 2015-04-22 /pmc/articles/PMC4420049/ /pubmed/25995932 http://dx.doi.org/10.1107/S2056989015006891 Text en © Devarajegowda et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Devarajegowda, H. C. Suchetan, P. A. Sreenivasa, S. Srinivasa, H. T. Palakshamurthy, B. S. Crystal structure of bis(4-methoxyphenyl) malonate |
title | Crystal structure of bis(4-methoxyphenyl) malonate |
title_full | Crystal structure of bis(4-methoxyphenyl) malonate |
title_fullStr | Crystal structure of bis(4-methoxyphenyl) malonate |
title_full_unstemmed | Crystal structure of bis(4-methoxyphenyl) malonate |
title_short | Crystal structure of bis(4-methoxyphenyl) malonate |
title_sort | crystal structure of bis(4-methoxyphenyl) malonate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420049/ https://www.ncbi.nlm.nih.gov/pubmed/25995932 http://dx.doi.org/10.1107/S2056989015006891 |
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