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Crystal structure of [2-(triethylammonio)ethyl][(2,4,6-triisopropylphenyl)sulfonyl]amide tetrahydrate
The zwitterionic title compound, C(23)H(42)N(2)O(2)S·4H(2)O, crystallized as a tetrahydrate from a solution of N-[(2,4,6-triisopropylphenyl)sulfonyl]aziridine in triethylamine, diethyl ether and pentane in the presence of moist air. It is formed by a nucleophillic ring-opening that is assumed...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420053/ https://www.ncbi.nlm.nih.gov/pubmed/25995881 http://dx.doi.org/10.1107/S2056989015008105 |
Sumario: | The zwitterionic title compound, C(23)H(42)N(2)O(2)S·4H(2)O, crystallized as a tetrahydrate from a solution of N-[(2,4,6-triisopropylphenyl)sulfonyl]aziridine in triethylamine, diethyl ether and pentane in the presence of moist air. It is formed by a nucleophillic ring-opening that is assumed to be reversible. The molecular structure shows a major disorder of the triisopropylphenyl group over two equally occupied locations. An interesting feature is the uncommon hydrate structure, exhibiting a tape-like motif which can be classified as a transition of the one-dimensional T4(2)6(2) motif into the two-dimensional L4(6)5(7)6(8) motif. |
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