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Crystal structure of [2-(triethylammonio)ethyl][(2,4,6-triisopropylphenyl)sulfonyl]amide tetrahydrate
The zwitterionic title compound, C(23)H(42)N(2)O(2)S·4H(2)O, crystallized as a tetrahydrate from a solution of N-[(2,4,6-triisopropylphenyl)sulfonyl]aziridine in triethylamine, diethyl ether and pentane in the presence of moist air. It is formed by a nucleophillic ring-opening that is assumed...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2015
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420053/ https://www.ncbi.nlm.nih.gov/pubmed/25995881 http://dx.doi.org/10.1107/S2056989015008105 |
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author | Golz, C. Strohmann, C. |
author_facet | Golz, C. Strohmann, C. |
author_sort | Golz, C. |
collection | PubMed |
description | The zwitterionic title compound, C(23)H(42)N(2)O(2)S·4H(2)O, crystallized as a tetrahydrate from a solution of N-[(2,4,6-triisopropylphenyl)sulfonyl]aziridine in triethylamine, diethyl ether and pentane in the presence of moist air. It is formed by a nucleophillic ring-opening that is assumed to be reversible. The molecular structure shows a major disorder of the triisopropylphenyl group over two equally occupied locations. An interesting feature is the uncommon hydrate structure, exhibiting a tape-like motif which can be classified as a transition of the one-dimensional T4(2)6(2) motif into the two-dimensional L4(6)5(7)6(8) motif. |
format | Online Article Text |
id | pubmed-4420053 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44200532015-05-20 Crystal structure of [2-(triethylammonio)ethyl][(2,4,6-triisopropylphenyl)sulfonyl]amide tetrahydrate Golz, C. Strohmann, C. Acta Crystallogr E Crystallogr Commun Research Communications The zwitterionic title compound, C(23)H(42)N(2)O(2)S·4H(2)O, crystallized as a tetrahydrate from a solution of N-[(2,4,6-triisopropylphenyl)sulfonyl]aziridine in triethylamine, diethyl ether and pentane in the presence of moist air. It is formed by a nucleophillic ring-opening that is assumed to be reversible. The molecular structure shows a major disorder of the triisopropylphenyl group over two equally occupied locations. An interesting feature is the uncommon hydrate structure, exhibiting a tape-like motif which can be classified as a transition of the one-dimensional T4(2)6(2) motif into the two-dimensional L4(6)5(7)6(8) motif. International Union of Crystallography 2015-04-30 /pmc/articles/PMC4420053/ /pubmed/25995881 http://dx.doi.org/10.1107/S2056989015008105 Text en © Golz and Strohmann 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Golz, C. Strohmann, C. Crystal structure of [2-(triethylammonio)ethyl][(2,4,6-triisopropylphenyl)sulfonyl]amide tetrahydrate |
title | Crystal structure of [2-(triethylammonio)ethyl][(2,4,6-triisopropylphenyl)sulfonyl]amide tetrahydrate |
title_full | Crystal structure of [2-(triethylammonio)ethyl][(2,4,6-triisopropylphenyl)sulfonyl]amide tetrahydrate |
title_fullStr | Crystal structure of [2-(triethylammonio)ethyl][(2,4,6-triisopropylphenyl)sulfonyl]amide tetrahydrate |
title_full_unstemmed | Crystal structure of [2-(triethylammonio)ethyl][(2,4,6-triisopropylphenyl)sulfonyl]amide tetrahydrate |
title_short | Crystal structure of [2-(triethylammonio)ethyl][(2,4,6-triisopropylphenyl)sulfonyl]amide tetrahydrate |
title_sort | crystal structure of [2-(triethylammonio)ethyl][(2,4,6-triisopropylphenyl)sulfonyl]amide tetrahydrate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420053/ https://www.ncbi.nlm.nih.gov/pubmed/25995881 http://dx.doi.org/10.1107/S2056989015008105 |
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