Cargando…

Crystal structure of [2-(tri­ethyl­ammonio)­eth­yl][(2,4,6-triiso­propyl­phen­yl)sulfon­yl]amide tetra­hydrate

The zwitterionic title compound, C(23)H(42)N(2)O(2)S·4H(2)O, crystallized as a tetrahydrate from a solution of N-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine in tri­ethyl­amine, diethyl ether and pentane in the presence of moist air. It is formed by a nucleophillic ring-opening that is assumed...

Descripción completa

Detalles Bibliográficos
Autores principales: Golz, C., Strohmann, C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420053/
https://www.ncbi.nlm.nih.gov/pubmed/25995881
http://dx.doi.org/10.1107/S2056989015008105
_version_ 1782369659024048128
author Golz, C.
Strohmann, C.
author_facet Golz, C.
Strohmann, C.
author_sort Golz, C.
collection PubMed
description The zwitterionic title compound, C(23)H(42)N(2)O(2)S·4H(2)O, crystallized as a tetrahydrate from a solution of N-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine in tri­ethyl­amine, diethyl ether and pentane in the presence of moist air. It is formed by a nucleophillic ring-opening that is assumed to be reversible. The mol­ecular structure shows a major disorder of the triiso­propyl­phenyl group over two equally occupied locations. An inter­esting feature is the uncommon hydrate structure, exhibiting a tape-like motif which can be classified as a transition of the one-dimensional T4(2)6(2) motif into the two-dimensional L4(6)5(7)6(8) motif.
format Online
Article
Text
id pubmed-4420053
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-44200532015-05-20 Crystal structure of [2-(tri­ethyl­ammonio)­eth­yl][(2,4,6-triiso­propyl­phen­yl)sulfon­yl]amide tetra­hydrate Golz, C. Strohmann, C. Acta Crystallogr E Crystallogr Commun Research Communications The zwitterionic title compound, C(23)H(42)N(2)O(2)S·4H(2)O, crystallized as a tetrahydrate from a solution of N-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine in tri­ethyl­amine, diethyl ether and pentane in the presence of moist air. It is formed by a nucleophillic ring-opening that is assumed to be reversible. The mol­ecular structure shows a major disorder of the triiso­propyl­phenyl group over two equally occupied locations. An inter­esting feature is the uncommon hydrate structure, exhibiting a tape-like motif which can be classified as a transition of the one-dimensional T4(2)6(2) motif into the two-dimensional L4(6)5(7)6(8) motif. International Union of Crystallography 2015-04-30 /pmc/articles/PMC4420053/ /pubmed/25995881 http://dx.doi.org/10.1107/S2056989015008105 Text en © Golz and Strohmann 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Golz, C.
Strohmann, C.
Crystal structure of [2-(tri­ethyl­ammonio)­eth­yl][(2,4,6-triiso­propyl­phen­yl)sulfon­yl]amide tetra­hydrate
title Crystal structure of [2-(tri­ethyl­ammonio)­eth­yl][(2,4,6-triiso­propyl­phen­yl)sulfon­yl]amide tetra­hydrate
title_full Crystal structure of [2-(tri­ethyl­ammonio)­eth­yl][(2,4,6-triiso­propyl­phen­yl)sulfon­yl]amide tetra­hydrate
title_fullStr Crystal structure of [2-(tri­ethyl­ammonio)­eth­yl][(2,4,6-triiso­propyl­phen­yl)sulfon­yl]amide tetra­hydrate
title_full_unstemmed Crystal structure of [2-(tri­ethyl­ammonio)­eth­yl][(2,4,6-triiso­propyl­phen­yl)sulfon­yl]amide tetra­hydrate
title_short Crystal structure of [2-(tri­ethyl­ammonio)­eth­yl][(2,4,6-triiso­propyl­phen­yl)sulfon­yl]amide tetra­hydrate
title_sort crystal structure of [2-(tri­ethyl­ammonio)­eth­yl][(2,4,6-triiso­propyl­phen­yl)sulfon­yl]amide tetra­hydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420053/
https://www.ncbi.nlm.nih.gov/pubmed/25995881
http://dx.doi.org/10.1107/S2056989015008105
work_keys_str_mv AT golzc crystalstructureof2triethylammonioethyl246triisopropylphenylsulfonylamidetetrahydrate
AT strohmannc crystalstructureof2triethylammonioethyl246triisopropylphenylsulfonylamidetetrahydrate