Cargando…

Crystal structure of (4-fluoro­phenyl-κC (1))iodido­(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)palladium(II)

In the title compound, [Pd(C(6)H(4)F)I(C(6)H(16)N(2))], the Pd(II) atom is coordinated by two N atoms from the N,N,N′,N′-tetra­methyl­ethylenedi­amine ligand, a C atom of the 4-fluoro­phenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-sq...

Descripción completa

Detalles Bibliográficos
Autores principales: Yan, Jin-Jin, Zheng, Chang-Ge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420056/
https://www.ncbi.nlm.nih.gov/pubmed/25995896
http://dx.doi.org/10.1107/S2056989015008014
Descripción
Sumario:In the title compound, [Pd(C(6)H(4)F)I(C(6)H(16)N(2))], the Pd(II) atom is coordinated by two N atoms from the N,N,N′,N′-tetra­methyl­ethylenedi­amine ligand, a C atom of the 4-fluoro­phenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-squares plane through the ligand donor atoms of 0.0159 (2) Å. The angles about the Pd(II) atom range from 83.35 (16) to 178.59 (11)°. In the crystal, weak C—H⋯F and C—H⋯I hydrogen bonds link the mol­ecules into sheets in the bc plane.