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Crystal structure of (4-fluorophenyl-κC (1))iodido(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)palladium(II)
In the title compound, [Pd(C(6)H(4)F)I(C(6)H(16)N(2))], the Pd(II) atom is coordinated by two N atoms from the N,N,N′,N′-tetramethylethylenediamine ligand, a C atom of the 4-fluorophenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-sq...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420056/ https://www.ncbi.nlm.nih.gov/pubmed/25995896 http://dx.doi.org/10.1107/S2056989015008014 |
Sumario: | In the title compound, [Pd(C(6)H(4)F)I(C(6)H(16)N(2))], the Pd(II) atom is coordinated by two N atoms from the N,N,N′,N′-tetramethylethylenediamine ligand, a C atom of the 4-fluorophenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-squares plane through the ligand donor atoms of 0.0159 (2) Å. The angles about the Pd(II) atom range from 83.35 (16) to 178.59 (11)°. In the crystal, weak C—H⋯F and C—H⋯I hydrogen bonds link the molecules into sheets in the bc plane. |
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