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Crystal structure of (4-fluorophenyl-κC (1))iodido(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)palladium(II)
In the title compound, [Pd(C(6)H(4)F)I(C(6)H(16)N(2))], the Pd(II) atom is coordinated by two N atoms from the N,N,N′,N′-tetramethylethylenediamine ligand, a C atom of the 4-fluorophenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-sq...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420056/ https://www.ncbi.nlm.nih.gov/pubmed/25995896 http://dx.doi.org/10.1107/S2056989015008014 |
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author | Yan, Jin-Jin Zheng, Chang-Ge |
author_facet | Yan, Jin-Jin Zheng, Chang-Ge |
author_sort | Yan, Jin-Jin |
collection | PubMed |
description | In the title compound, [Pd(C(6)H(4)F)I(C(6)H(16)N(2))], the Pd(II) atom is coordinated by two N atoms from the N,N,N′,N′-tetramethylethylenediamine ligand, a C atom of the 4-fluorophenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-squares plane through the ligand donor atoms of 0.0159 (2) Å. The angles about the Pd(II) atom range from 83.35 (16) to 178.59 (11)°. In the crystal, weak C—H⋯F and C—H⋯I hydrogen bonds link the molecules into sheets in the bc plane. |
format | Online Article Text |
id | pubmed-4420056 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44200562015-05-20 Crystal structure of (4-fluorophenyl-κC (1))iodido(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)palladium(II) Yan, Jin-Jin Zheng, Chang-Ge Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, [Pd(C(6)H(4)F)I(C(6)H(16)N(2))], the Pd(II) atom is coordinated by two N atoms from the N,N,N′,N′-tetramethylethylenediamine ligand, a C atom of the 4-fluorophenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-squares plane through the ligand donor atoms of 0.0159 (2) Å. The angles about the Pd(II) atom range from 83.35 (16) to 178.59 (11)°. In the crystal, weak C—H⋯F and C—H⋯I hydrogen bonds link the molecules into sheets in the bc plane. International Union of Crystallography 2015-04-30 /pmc/articles/PMC4420056/ /pubmed/25995896 http://dx.doi.org/10.1107/S2056989015008014 Text en © Yan and Zheng 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Yan, Jin-Jin Zheng, Chang-Ge Crystal structure of (4-fluorophenyl-κC (1))iodido(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)palladium(II) |
title | Crystal structure of (4-fluorophenyl-κC
(1))iodido(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)palladium(II) |
title_full | Crystal structure of (4-fluorophenyl-κC
(1))iodido(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)palladium(II) |
title_fullStr | Crystal structure of (4-fluorophenyl-κC
(1))iodido(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)palladium(II) |
title_full_unstemmed | Crystal structure of (4-fluorophenyl-κC
(1))iodido(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)palladium(II) |
title_short | Crystal structure of (4-fluorophenyl-κC
(1))iodido(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)palladium(II) |
title_sort | crystal structure of (4-fluorophenyl-κc
(1))iodido(n,n,n′,n′-tetramethylethylenediamine-κ(2)
n,n′)palladium(ii) |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420056/ https://www.ncbi.nlm.nih.gov/pubmed/25995896 http://dx.doi.org/10.1107/S2056989015008014 |
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