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Crystal structure of (4-fluoro­phenyl-κC (1))iodido­(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)palladium(II)

In the title compound, [Pd(C(6)H(4)F)I(C(6)H(16)N(2))], the Pd(II) atom is coordinated by two N atoms from the N,N,N′,N′-tetra­methyl­ethylenedi­amine ligand, a C atom of the 4-fluoro­phenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-sq...

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Detalles Bibliográficos
Autores principales: Yan, Jin-Jin, Zheng, Chang-Ge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420056/
https://www.ncbi.nlm.nih.gov/pubmed/25995896
http://dx.doi.org/10.1107/S2056989015008014
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author Yan, Jin-Jin
Zheng, Chang-Ge
author_facet Yan, Jin-Jin
Zheng, Chang-Ge
author_sort Yan, Jin-Jin
collection PubMed
description In the title compound, [Pd(C(6)H(4)F)I(C(6)H(16)N(2))], the Pd(II) atom is coordinated by two N atoms from the N,N,N′,N′-tetra­methyl­ethylenedi­amine ligand, a C atom of the 4-fluoro­phenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-squares plane through the ligand donor atoms of 0.0159 (2) Å. The angles about the Pd(II) atom range from 83.35 (16) to 178.59 (11)°. In the crystal, weak C—H⋯F and C—H⋯I hydrogen bonds link the mol­ecules into sheets in the bc plane.
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spelling pubmed-44200562015-05-20 Crystal structure of (4-fluoro­phenyl-κC (1))iodido­(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)palladium(II) Yan, Jin-Jin Zheng, Chang-Ge Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, [Pd(C(6)H(4)F)I(C(6)H(16)N(2))], the Pd(II) atom is coordinated by two N atoms from the N,N,N′,N′-tetra­methyl­ethylenedi­amine ligand, a C atom of the 4-fluoro­phenyl group and an iodide ligand in a distorted square-planar geometry, with an average deviation from the least-squares plane through the ligand donor atoms of 0.0159 (2) Å. The angles about the Pd(II) atom range from 83.35 (16) to 178.59 (11)°. In the crystal, weak C—H⋯F and C—H⋯I hydrogen bonds link the mol­ecules into sheets in the bc plane. International Union of Crystallography 2015-04-30 /pmc/articles/PMC4420056/ /pubmed/25995896 http://dx.doi.org/10.1107/S2056989015008014 Text en © Yan and Zheng 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Yan, Jin-Jin
Zheng, Chang-Ge
Crystal structure of (4-fluoro­phenyl-κC (1))iodido­(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)palladium(II)
title Crystal structure of (4-fluoro­phenyl-κC (1))iodido­(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)palladium(II)
title_full Crystal structure of (4-fluoro­phenyl-κC (1))iodido­(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)palladium(II)
title_fullStr Crystal structure of (4-fluoro­phenyl-κC (1))iodido­(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)palladium(II)
title_full_unstemmed Crystal structure of (4-fluoro­phenyl-κC (1))iodido­(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)palladium(II)
title_short Crystal structure of (4-fluoro­phenyl-κC (1))iodido­(N,N,N′,N′-tetra­methyl­ethylenedi­amine-κ(2) N,N′)palladium(II)
title_sort crystal structure of (4-fluoro­phenyl-κc (1))iodido­(n,n,n′,n′-tetra­methyl­ethylenedi­amine-κ(2) n,n′)palladium(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420056/
https://www.ncbi.nlm.nih.gov/pubmed/25995896
http://dx.doi.org/10.1107/S2056989015008014
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