Crystal structure of poly[di-μ-aqua-{5-[(1Z)-2-(4-chloro­phen­yl)-1-cyano­ethenyl]-1,2,3,4-tetra­zol-1-ido-κN (1)}sodium]

In the title compound, [Na(C(10)H(5)ClN(5))(H(2)O)(2)](n), infinite chains of [Na(H(2)O)(2)](+) cations having a diamond-shaped cross-section and running parallel to the b axis are formed. O—H⋯N hydrogen bonds to the anions generate layers parallel to (100) which have the chloro­benzene­cyano­etheny...

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Detalles Bibliográficos
Autores principales: Mague, Joel T., Mohamed, Shaaban K., Akkurt, Mehmet, El-Saghier, Ahmed M. M., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420058/
https://www.ncbi.nlm.nih.gov/pubmed/25995885
http://dx.doi.org/10.1107/S2056989015006325
Descripción
Sumario:In the title compound, [Na(C(10)H(5)ClN(5))(H(2)O)(2)](n), infinite chains of [Na(H(2)O)(2)](+) cations having a diamond-shaped cross-section and running parallel to the b axis are formed. O—H⋯N hydrogen bonds to the anions generate layers parallel to (100) which have the chloro­benzene­cyano­ethenyl substituents protruding from both surfaces. The sodium ion makes a short contact of 2.4801 (13) Å with the N atom of the tetra­zolide ring which is syn to the cyano N atom.

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