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Crystal structure of (E)-1-(4-tert-butylphenyl)-2-(4-iodophenyl)ethene
The title compound, C(18)H(19)I, crystallized with two independent molecules (A and B) in the asymmetric unit. Both molecules have an E conformation about the bridging C=C bond. They differ in the orientation of the two benzene rings; the dihedral angle being 12.3 (5)° in molecule A, but only 1.0...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420064/ https://www.ncbi.nlm.nih.gov/pubmed/25995920 http://dx.doi.org/10.1107/S2056989015007185 |
Sumario: | The title compound, C(18)H(19)I, crystallized with two independent molecules (A and B) in the asymmetric unit. Both molecules have an E conformation about the bridging C=C bond. They differ in the orientation of the two benzene rings; the dihedral angle being 12.3 (5)° in molecule A, but only 1.0 (6)° in molecule B. In the crystal, the individual molecules are linked by C—I⋯π interactions forming zigzag A and zigzag B chains propagating along [001]. The structure was refined as an inversion twin [Flack parameter = 0.48 (2)]. |
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