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Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-dihydro-4H-pyrazol-4-ylidene)propyl]benzenesulfonohydrazide
The title compound, C(19)H(20)N(4)O(3)S, was synthesized by refluxing equimolar amounts of 1-phenyl-3-methyl-4-propionylpyrazol-5-one and benzenesulfonyl hydrazide in ethanol. The compound crystallizes in the keto form and the carbonyl O atom forms an intramolecular N—H⋯O hydrogen bond with the ne...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420066/ https://www.ncbi.nlm.nih.gov/pubmed/25995862 http://dx.doi.org/10.1107/S2056989015007094 |
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author | He, Chuan-Chuan Xu, Guan-Cheng |
author_facet | He, Chuan-Chuan Xu, Guan-Cheng |
author_sort | He, Chuan-Chuan |
collection | PubMed |
description | The title compound, C(19)H(20)N(4)O(3)S, was synthesized by refluxing equimolar amounts of 1-phenyl-3-methyl-4-propionylpyrazol-5-one and benzenesulfonyl hydrazide in ethanol. The compound crystallizes in the keto form and the carbonyl O atom forms an intramolecular N—H⋯O hydrogen bond with the neighbouring NH group. There is also C—H⋯O short contact involving the neighbouring phenyl ring. Probably as a result of this, the phenyl ring is inclined to the pyrazolone ring by only 7.58 (12)°. The dihedral angle between the phenyl ring and the benzenesulfonyl ring is 22.78 (11)°. In the crystal, molecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(14) ring motif. The dimers are linked via pairs of C—H⋯O hydrogen bonds, forming chains propagating along [100]. |
format | Online Article Text |
id | pubmed-4420066 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44200662015-05-20 Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-dihydro-4H-pyrazol-4-ylidene)propyl]benzenesulfonohydrazide He, Chuan-Chuan Xu, Guan-Cheng Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(19)H(20)N(4)O(3)S, was synthesized by refluxing equimolar amounts of 1-phenyl-3-methyl-4-propionylpyrazol-5-one and benzenesulfonyl hydrazide in ethanol. The compound crystallizes in the keto form and the carbonyl O atom forms an intramolecular N—H⋯O hydrogen bond with the neighbouring NH group. There is also C—H⋯O short contact involving the neighbouring phenyl ring. Probably as a result of this, the phenyl ring is inclined to the pyrazolone ring by only 7.58 (12)°. The dihedral angle between the phenyl ring and the benzenesulfonyl ring is 22.78 (11)°. In the crystal, molecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(14) ring motif. The dimers are linked via pairs of C—H⋯O hydrogen bonds, forming chains propagating along [100]. International Union of Crystallography 2015-04-15 /pmc/articles/PMC4420066/ /pubmed/25995862 http://dx.doi.org/10.1107/S2056989015007094 Text en © He and Xu 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications He, Chuan-Chuan Xu, Guan-Cheng Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-dihydro-4H-pyrazol-4-ylidene)propyl]benzenesulfonohydrazide |
title | Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-dihydro-4H-pyrazol-4-ylidene)propyl]benzenesulfonohydrazide |
title_full | Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-dihydro-4H-pyrazol-4-ylidene)propyl]benzenesulfonohydrazide |
title_fullStr | Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-dihydro-4H-pyrazol-4-ylidene)propyl]benzenesulfonohydrazide |
title_full_unstemmed | Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-dihydro-4H-pyrazol-4-ylidene)propyl]benzenesulfonohydrazide |
title_short | Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-dihydro-4H-pyrazol-4-ylidene)propyl]benzenesulfonohydrazide |
title_sort | crystal structure of (z)-n′-[1-(3-methyl-5-oxo-1-phenyl-1,5-dihydro-4h-pyrazol-4-ylidene)propyl]benzenesulfonohydrazide |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420066/ https://www.ncbi.nlm.nih.gov/pubmed/25995862 http://dx.doi.org/10.1107/S2056989015007094 |
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