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Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-di­hydro-4H-pyrazol-4-yl­idene)prop­yl]benzene­sulfono­hydrazide

The title compound, C(19)H(20)N(4)O(3)S, was synthesized by refluxing equimolar amounts of 1-phenyl-3-methyl-4-propionylpyrazol-5-one and benzene­sulfonyl hydrazide in ethanol. The compound crystallizes in the keto form and the carbonyl O atom forms an intra­molecular N—H⋯O hydrogen bond with the ne...

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Autores principales: He, Chuan-Chuan, Xu, Guan-Cheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420066/
https://www.ncbi.nlm.nih.gov/pubmed/25995862
http://dx.doi.org/10.1107/S2056989015007094
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author He, Chuan-Chuan
Xu, Guan-Cheng
author_facet He, Chuan-Chuan
Xu, Guan-Cheng
author_sort He, Chuan-Chuan
collection PubMed
description The title compound, C(19)H(20)N(4)O(3)S, was synthesized by refluxing equimolar amounts of 1-phenyl-3-methyl-4-propionylpyrazol-5-one and benzene­sulfonyl hydrazide in ethanol. The compound crystallizes in the keto form and the carbonyl O atom forms an intra­molecular N—H⋯O hydrogen bond with the neighbouring NH group. There is also C—H⋯O short contact involving the neighbouring phenyl ring. Probably as a result of this, the phenyl ring is inclined to the pyrazolone ring by only 7.58 (12)°. The dihedral angle between the phenyl ring and the benzene­sulfonyl ring is 22.78 (11)°. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(14) ring motif. The dimers are linked via pairs of C—H⋯O hydrogen bonds, forming chains propagating along [100].
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spelling pubmed-44200662015-05-20 Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-di­hydro-4H-pyrazol-4-yl­idene)prop­yl]benzene­sulfono­hydrazide He, Chuan-Chuan Xu, Guan-Cheng Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(19)H(20)N(4)O(3)S, was synthesized by refluxing equimolar amounts of 1-phenyl-3-methyl-4-propionylpyrazol-5-one and benzene­sulfonyl hydrazide in ethanol. The compound crystallizes in the keto form and the carbonyl O atom forms an intra­molecular N—H⋯O hydrogen bond with the neighbouring NH group. There is also C—H⋯O short contact involving the neighbouring phenyl ring. Probably as a result of this, the phenyl ring is inclined to the pyrazolone ring by only 7.58 (12)°. The dihedral angle between the phenyl ring and the benzene­sulfonyl ring is 22.78 (11)°. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(14) ring motif. The dimers are linked via pairs of C—H⋯O hydrogen bonds, forming chains propagating along [100]. International Union of Crystallography 2015-04-15 /pmc/articles/PMC4420066/ /pubmed/25995862 http://dx.doi.org/10.1107/S2056989015007094 Text en © He and Xu 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
He, Chuan-Chuan
Xu, Guan-Cheng
Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-di­hydro-4H-pyrazol-4-yl­idene)prop­yl]benzene­sulfono­hydrazide
title Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-di­hydro-4H-pyrazol-4-yl­idene)prop­yl]benzene­sulfono­hydrazide
title_full Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-di­hydro-4H-pyrazol-4-yl­idene)prop­yl]benzene­sulfono­hydrazide
title_fullStr Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-di­hydro-4H-pyrazol-4-yl­idene)prop­yl]benzene­sulfono­hydrazide
title_full_unstemmed Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-di­hydro-4H-pyrazol-4-yl­idene)prop­yl]benzene­sulfono­hydrazide
title_short Crystal structure of (Z)-N′-[1-(3-methyl-5-oxo-1-phenyl-1,5-di­hydro-4H-pyrazol-4-yl­idene)prop­yl]benzene­sulfono­hydrazide
title_sort crystal structure of (z)-n′-[1-(3-methyl-5-oxo-1-phenyl-1,5-di­hydro-4h-pyrazol-4-yl­idene)prop­yl]benzene­sulfono­hydrazide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420066/
https://www.ncbi.nlm.nih.gov/pubmed/25995862
http://dx.doi.org/10.1107/S2056989015007094
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