Crystal structure of 2-{(E)-[(2-hy­droxy­phen­yl)iminium­yl]meth­yl}-4-methyl­phenolate

The title compound, C(14)H(13)NO(2), exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intra­molecular N—H⋯O hydrogen bond generate S(6) and S(5) loops. In the crys...

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Autores principales: Shalini, Suresh, Girija, C. R., Jotani, Mukesh M., Sathish, C. D., Venkatesha, T. V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420074/
https://www.ncbi.nlm.nih.gov/pubmed/25995908
http://dx.doi.org/10.1107/S2056989015006374
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author Shalini, Suresh
Girija, C. R.
Jotani, Mukesh M.
Sathish, C. D.
Venkatesha, T. V.
author_facet Shalini, Suresh
Girija, C. R.
Jotani, Mukesh M.
Sathish, C. D.
Venkatesha, T. V.
author_sort Shalini, Suresh
collection PubMed
description The title compound, C(14)H(13)NO(2), exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intra­molecular N—H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, mol­ecules are connected by O—H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction.
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spelling pubmed-44200742015-05-20 Crystal structure of 2-{(E)-[(2-hy­droxy­phen­yl)iminium­yl]meth­yl}-4-methyl­phenolate Shalini, Suresh Girija, C. R. Jotani, Mukesh M. Sathish, C. D. Venkatesha, T. V. Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(14)H(13)NO(2), exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intra­molecular N—H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, mol­ecules are connected by O—H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction. International Union of Crystallography 2015-04-09 /pmc/articles/PMC4420074/ /pubmed/25995908 http://dx.doi.org/10.1107/S2056989015006374 Text en © Shalini et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Shalini, Suresh
Girija, C. R.
Jotani, Mukesh M.
Sathish, C. D.
Venkatesha, T. V.
Crystal structure of 2-{(E)-[(2-hy­droxy­phen­yl)iminium­yl]meth­yl}-4-methyl­phenolate
title Crystal structure of 2-{(E)-[(2-hy­droxy­phen­yl)iminium­yl]meth­yl}-4-methyl­phenolate
title_full Crystal structure of 2-{(E)-[(2-hy­droxy­phen­yl)iminium­yl]meth­yl}-4-methyl­phenolate
title_fullStr Crystal structure of 2-{(E)-[(2-hy­droxy­phen­yl)iminium­yl]meth­yl}-4-methyl­phenolate
title_full_unstemmed Crystal structure of 2-{(E)-[(2-hy­droxy­phen­yl)iminium­yl]meth­yl}-4-methyl­phenolate
title_short Crystal structure of 2-{(E)-[(2-hy­droxy­phen­yl)iminium­yl]meth­yl}-4-methyl­phenolate
title_sort crystal structure of 2-{(e)-[(2-hy­droxy­phen­yl)iminium­yl]meth­yl}-4-methyl­phenolate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420074/
https://www.ncbi.nlm.nih.gov/pubmed/25995908
http://dx.doi.org/10.1107/S2056989015006374
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