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Crystal structure of 2-(11-oxo-10H,11H-indeno[1,2-b]chromen-10-yl)-2,3-dihydro-1H-indene-1,3-dione
In the title molecule, C(25)H(14)O(4), the fused-ring system consisting of four rings is approximately planar, with a dihedral angle of 9.62 (5)° between the planes of the indene ring system and the benzene ring. The dihydroindene-1,3-dione unit makes a dihedral angle of 63.50 (2)° with the mean...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420077/ https://www.ncbi.nlm.nih.gov/pubmed/25995934 http://dx.doi.org/10.1107/S2056989015007495 |
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author | Mague, Joel T. Mohamed, Shaaban K. Akkurt, Mehmet Abdelhamid, Antanr A. Albayati, Mustafa R. |
author_facet | Mague, Joel T. Mohamed, Shaaban K. Akkurt, Mehmet Abdelhamid, Antanr A. Albayati, Mustafa R. |
author_sort | Mague, Joel T. |
collection | PubMed |
description | In the title molecule, C(25)H(14)O(4), the fused-ring system consisting of four rings is approximately planar, with a dihedral angle of 9.62 (5)° between the planes of the indene ring system and the benzene ring. The dihydroindene-1,3-dione unit makes a dihedral angle of 63.50 (2)° with the mean plane of the fused-ring system. A weak C—H⋯O interaction organizes the molecules into a helical chain along the b axis. In addition, there is a π–π stacking interaction between the five-membered rings of adjacent fused-ring systems, with a centroid–centroid distance of 3.666 (1) Å. |
format | Online Article Text |
id | pubmed-4420077 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44200772015-05-20 Crystal structure of 2-(11-oxo-10H,11H-indeno[1,2-b]chromen-10-yl)-2,3-dihydro-1H-indene-1,3-dione Mague, Joel T. Mohamed, Shaaban K. Akkurt, Mehmet Abdelhamid, Antanr A. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Data Reports In the title molecule, C(25)H(14)O(4), the fused-ring system consisting of four rings is approximately planar, with a dihedral angle of 9.62 (5)° between the planes of the indene ring system and the benzene ring. The dihydroindene-1,3-dione unit makes a dihedral angle of 63.50 (2)° with the mean plane of the fused-ring system. A weak C—H⋯O interaction organizes the molecules into a helical chain along the b axis. In addition, there is a π–π stacking interaction between the five-membered rings of adjacent fused-ring systems, with a centroid–centroid distance of 3.666 (1) Å. International Union of Crystallography 2015-04-22 /pmc/articles/PMC4420077/ /pubmed/25995934 http://dx.doi.org/10.1107/S2056989015007495 Text en © Mague et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Mague, Joel T. Mohamed, Shaaban K. Akkurt, Mehmet Abdelhamid, Antanr A. Albayati, Mustafa R. Crystal structure of 2-(11-oxo-10H,11H-indeno[1,2-b]chromen-10-yl)-2,3-dihydro-1H-indene-1,3-dione |
title | Crystal structure of 2-(11-oxo-10H,11H-indeno[1,2-b]chromen-10-yl)-2,3-dihydro-1H-indene-1,3-dione |
title_full | Crystal structure of 2-(11-oxo-10H,11H-indeno[1,2-b]chromen-10-yl)-2,3-dihydro-1H-indene-1,3-dione |
title_fullStr | Crystal structure of 2-(11-oxo-10H,11H-indeno[1,2-b]chromen-10-yl)-2,3-dihydro-1H-indene-1,3-dione |
title_full_unstemmed | Crystal structure of 2-(11-oxo-10H,11H-indeno[1,2-b]chromen-10-yl)-2,3-dihydro-1H-indene-1,3-dione |
title_short | Crystal structure of 2-(11-oxo-10H,11H-indeno[1,2-b]chromen-10-yl)-2,3-dihydro-1H-indene-1,3-dione |
title_sort | crystal structure of 2-(11-oxo-10h,11h-indeno[1,2-b]chromen-10-yl)-2,3-dihydro-1h-indene-1,3-dione |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420077/ https://www.ncbi.nlm.nih.gov/pubmed/25995934 http://dx.doi.org/10.1107/S2056989015007495 |
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