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Crystal structure of 2-(11-oxo-10H,11H-indeno­[1,2-b]chromen-10-yl)-2,3-di­hydro-1H-indene-1,3-dione

In the title mol­ecule, C(25)H(14)O(4), the fused-ring system consisting of four rings is approximately planar, with a dihedral angle of 9.62 (5)° between the planes of the indene ring system and the benzene ring. The di­hydro­indene-1,3-dione unit makes a dihedral angle of 63.50 (2)° with the mean...

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Autores principales: Mague, Joel T., Mohamed, Shaaban K., Akkurt, Mehmet, Abdelhamid, Antanr A., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420077/
https://www.ncbi.nlm.nih.gov/pubmed/25995934
http://dx.doi.org/10.1107/S2056989015007495
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author Mague, Joel T.
Mohamed, Shaaban K.
Akkurt, Mehmet
Abdelhamid, Antanr A.
Albayati, Mustafa R.
author_facet Mague, Joel T.
Mohamed, Shaaban K.
Akkurt, Mehmet
Abdelhamid, Antanr A.
Albayati, Mustafa R.
author_sort Mague, Joel T.
collection PubMed
description In the title mol­ecule, C(25)H(14)O(4), the fused-ring system consisting of four rings is approximately planar, with a dihedral angle of 9.62 (5)° between the planes of the indene ring system and the benzene ring. The di­hydro­indene-1,3-dione unit makes a dihedral angle of 63.50 (2)° with the mean plane of the fused-ring system. A weak C—H⋯O inter­action organizes the mol­ecules into a helical chain along the b axis. In addition, there is a π–π stacking inter­action between the five-membered rings of adjacent fused-ring systems, with a centroid–centroid distance of 3.666 (1) Å.
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spelling pubmed-44200772015-05-20 Crystal structure of 2-(11-oxo-10H,11H-indeno­[1,2-b]chromen-10-yl)-2,3-di­hydro-1H-indene-1,3-dione Mague, Joel T. Mohamed, Shaaban K. Akkurt, Mehmet Abdelhamid, Antanr A. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Data Reports In the title mol­ecule, C(25)H(14)O(4), the fused-ring system consisting of four rings is approximately planar, with a dihedral angle of 9.62 (5)° between the planes of the indene ring system and the benzene ring. The di­hydro­indene-1,3-dione unit makes a dihedral angle of 63.50 (2)° with the mean plane of the fused-ring system. A weak C—H⋯O inter­action organizes the mol­ecules into a helical chain along the b axis. In addition, there is a π–π stacking inter­action between the five-membered rings of adjacent fused-ring systems, with a centroid–centroid distance of 3.666 (1) Å. International Union of Crystallography 2015-04-22 /pmc/articles/PMC4420077/ /pubmed/25995934 http://dx.doi.org/10.1107/S2056989015007495 Text en © Mague et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Mague, Joel T.
Mohamed, Shaaban K.
Akkurt, Mehmet
Abdelhamid, Antanr A.
Albayati, Mustafa R.
Crystal structure of 2-(11-oxo-10H,11H-indeno­[1,2-b]chromen-10-yl)-2,3-di­hydro-1H-indene-1,3-dione
title Crystal structure of 2-(11-oxo-10H,11H-indeno­[1,2-b]chromen-10-yl)-2,3-di­hydro-1H-indene-1,3-dione
title_full Crystal structure of 2-(11-oxo-10H,11H-indeno­[1,2-b]chromen-10-yl)-2,3-di­hydro-1H-indene-1,3-dione
title_fullStr Crystal structure of 2-(11-oxo-10H,11H-indeno­[1,2-b]chromen-10-yl)-2,3-di­hydro-1H-indene-1,3-dione
title_full_unstemmed Crystal structure of 2-(11-oxo-10H,11H-indeno­[1,2-b]chromen-10-yl)-2,3-di­hydro-1H-indene-1,3-dione
title_short Crystal structure of 2-(11-oxo-10H,11H-indeno­[1,2-b]chromen-10-yl)-2,3-di­hydro-1H-indene-1,3-dione
title_sort crystal structure of 2-(11-oxo-10h,11h-indeno­[1,2-b]chromen-10-yl)-2,3-di­hydro-1h-indene-1,3-dione
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420077/
https://www.ncbi.nlm.nih.gov/pubmed/25995934
http://dx.doi.org/10.1107/S2056989015007495
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