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Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN (3))copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ(2) O:O′] dihydrate]
In the title polymeric complex, {[Cu(C(14)H(14)N(2)O(6))(C(3)H(4)N(2))(2)(H(2)O)]·2H(2)O}(n), the Cu(II) cation, located on a twofold rotation axis, is coordinated by one water molecule and two imidazole molecules as well as two symmetry-related 3-([4-[(2-carboxylatoethyl)carbamoyl]phenyl]form...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420079/ https://www.ncbi.nlm.nih.gov/pubmed/25995888 http://dx.doi.org/10.1107/S205698901500626X |
Sumario: | In the title polymeric complex, {[Cu(C(14)H(14)N(2)O(6))(C(3)H(4)N(2))(2)(H(2)O)]·2H(2)O}(n), the Cu(II) cation, located on a twofold rotation axis, is coordinated by one water molecule and two imidazole molecules as well as two symmetry-related 3-([4-[(2-carboxylatoethyl)carbamoyl]phenyl]formamido)propanoate dianions (L (2−)) in an approximately square-pyramidal geometry. The coordinating water molecule is located on a twofold rotation axis while the L (2−) anion sits about an inversion center. The L (2−) anions bridge the Cu(II) cations, forming polymeric chains propagating along the [101] direction. In the crystal, O—H⋯O, N—H⋯O hydrogen bonds and weak C—H⋯π interaction link the polymeric chains and the solvent water molecules into a three-dimensional supramolecular architecture. |
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