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Crystal structure of catena-poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-3-({4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl}formamido)­propano­ato-κ(2) O:O′] dihydrate]

In the title polymeric complex, {[Cu(C(14)H(14)N(2)O(6))(C(3)H(4)N(2))(2)(H(2)O)]·2H(2)O}(n), the Cu(II) cation, located on a twofold rotation axis, is coordinated by one water mol­ecule and two imidazole mol­ecules as well as two symmetry-related 3-([4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl]form...

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Detalles Bibliográficos
Autores principales: Liu, Yan, Xu, Liu-Yang, Zhang, Hong-Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420079/
https://www.ncbi.nlm.nih.gov/pubmed/25995888
http://dx.doi.org/10.1107/S205698901500626X
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author Liu, Yan
Xu, Liu-Yang
Zhang, Hong-Tao
author_facet Liu, Yan
Xu, Liu-Yang
Zhang, Hong-Tao
author_sort Liu, Yan
collection PubMed
description In the title polymeric complex, {[Cu(C(14)H(14)N(2)O(6))(C(3)H(4)N(2))(2)(H(2)O)]·2H(2)O}(n), the Cu(II) cation, located on a twofold rotation axis, is coordinated by one water mol­ecule and two imidazole mol­ecules as well as two symmetry-related 3-([4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl]formamido)­propano­ate dianions (L (2−)) in an approximately square-pyramidal geometry. The coordinating water mol­ecule is located on a twofold rotation axis while the L (2−) anion sits about an inversion center. The L (2−) anions bridge the Cu(II) cations, forming polymeric chains propagating along the [101] direction. In the crystal, O—H⋯O, N—H⋯O hydrogen bonds and weak C—H⋯π inter­action link the polymeric chains and the solvent water mol­ecules into a three-dimensional supra­molecular architecture.
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spelling pubmed-44200792015-05-20 Crystal structure of catena-poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-3-({4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl}formamido)­propano­ato-κ(2) O:O′] dihydrate] Liu, Yan Xu, Liu-Yang Zhang, Hong-Tao Acta Crystallogr E Crystallogr Commun Data Reports In the title polymeric complex, {[Cu(C(14)H(14)N(2)O(6))(C(3)H(4)N(2))(2)(H(2)O)]·2H(2)O}(n), the Cu(II) cation, located on a twofold rotation axis, is coordinated by one water mol­ecule and two imidazole mol­ecules as well as two symmetry-related 3-([4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl]formamido)­propano­ate dianions (L (2−)) in an approximately square-pyramidal geometry. The coordinating water mol­ecule is located on a twofold rotation axis while the L (2−) anion sits about an inversion center. The L (2−) anions bridge the Cu(II) cations, forming polymeric chains propagating along the [101] direction. In the crystal, O—H⋯O, N—H⋯O hydrogen bonds and weak C—H⋯π inter­action link the polymeric chains and the solvent water mol­ecules into a three-dimensional supra­molecular architecture. International Union of Crystallography 2015-04-11 /pmc/articles/PMC4420079/ /pubmed/25995888 http://dx.doi.org/10.1107/S205698901500626X Text en © Liu et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Liu, Yan
Xu, Liu-Yang
Zhang, Hong-Tao
Crystal structure of catena-poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-3-({4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl}formamido)­propano­ato-κ(2) O:O′] dihydrate]
title Crystal structure of catena-poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-3-({4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl}formamido)­propano­ato-κ(2) O:O′] dihydrate]
title_full Crystal structure of catena-poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-3-({4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl}formamido)­propano­ato-κ(2) O:O′] dihydrate]
title_fullStr Crystal structure of catena-poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-3-({4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl}formamido)­propano­ato-κ(2) O:O′] dihydrate]
title_full_unstemmed Crystal structure of catena-poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-3-({4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl}formamido)­propano­ato-κ(2) O:O′] dihydrate]
title_short Crystal structure of catena-poly[[[aqua­bis­(1H-imidazole-κN (3))copper(II)]-μ-3-({4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl}formamido)­propano­ato-κ(2) O:O′] dihydrate]
title_sort crystal structure of catena-poly[[[aqua­bis­(1h-imidazole-κn (3))copper(ii)]-μ-3-({4-[(2-carboxyl­atoeth­yl)carbamo­yl]phen­yl}formamido)­propano­ato-κ(2) o:o′] dihydrate]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420079/
https://www.ncbi.nlm.nih.gov/pubmed/25995888
http://dx.doi.org/10.1107/S205698901500626X
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