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Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN (3))copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ(2) O:O′] dihydrate]
In the title polymeric complex, {[Cu(C(14)H(14)N(2)O(6))(C(3)H(4)N(2))(2)(H(2)O)]·2H(2)O}(n), the Cu(II) cation, located on a twofold rotation axis, is coordinated by one water molecule and two imidazole molecules as well as two symmetry-related 3-([4-[(2-carboxylatoethyl)carbamoyl]phenyl]form...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420079/ https://www.ncbi.nlm.nih.gov/pubmed/25995888 http://dx.doi.org/10.1107/S205698901500626X |
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author | Liu, Yan Xu, Liu-Yang Zhang, Hong-Tao |
author_facet | Liu, Yan Xu, Liu-Yang Zhang, Hong-Tao |
author_sort | Liu, Yan |
collection | PubMed |
description | In the title polymeric complex, {[Cu(C(14)H(14)N(2)O(6))(C(3)H(4)N(2))(2)(H(2)O)]·2H(2)O}(n), the Cu(II) cation, located on a twofold rotation axis, is coordinated by one water molecule and two imidazole molecules as well as two symmetry-related 3-([4-[(2-carboxylatoethyl)carbamoyl]phenyl]formamido)propanoate dianions (L (2−)) in an approximately square-pyramidal geometry. The coordinating water molecule is located on a twofold rotation axis while the L (2−) anion sits about an inversion center. The L (2−) anions bridge the Cu(II) cations, forming polymeric chains propagating along the [101] direction. In the crystal, O—H⋯O, N—H⋯O hydrogen bonds and weak C—H⋯π interaction link the polymeric chains and the solvent water molecules into a three-dimensional supramolecular architecture. |
format | Online Article Text |
id | pubmed-4420079 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44200792015-05-20 Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN (3))copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ(2) O:O′] dihydrate] Liu, Yan Xu, Liu-Yang Zhang, Hong-Tao Acta Crystallogr E Crystallogr Commun Data Reports In the title polymeric complex, {[Cu(C(14)H(14)N(2)O(6))(C(3)H(4)N(2))(2)(H(2)O)]·2H(2)O}(n), the Cu(II) cation, located on a twofold rotation axis, is coordinated by one water molecule and two imidazole molecules as well as two symmetry-related 3-([4-[(2-carboxylatoethyl)carbamoyl]phenyl]formamido)propanoate dianions (L (2−)) in an approximately square-pyramidal geometry. The coordinating water molecule is located on a twofold rotation axis while the L (2−) anion sits about an inversion center. The L (2−) anions bridge the Cu(II) cations, forming polymeric chains propagating along the [101] direction. In the crystal, O—H⋯O, N—H⋯O hydrogen bonds and weak C—H⋯π interaction link the polymeric chains and the solvent water molecules into a three-dimensional supramolecular architecture. International Union of Crystallography 2015-04-11 /pmc/articles/PMC4420079/ /pubmed/25995888 http://dx.doi.org/10.1107/S205698901500626X Text en © Liu et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Liu, Yan Xu, Liu-Yang Zhang, Hong-Tao Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN (3))copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ(2) O:O′] dihydrate] |
title | Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN
(3))copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ(2)
O:O′] dihydrate] |
title_full | Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN
(3))copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ(2)
O:O′] dihydrate] |
title_fullStr | Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN
(3))copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ(2)
O:O′] dihydrate] |
title_full_unstemmed | Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN
(3))copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ(2)
O:O′] dihydrate] |
title_short | Crystal structure of catena-poly[[[aquabis(1H-imidazole-κN
(3))copper(II)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ(2)
O:O′] dihydrate] |
title_sort | crystal structure of catena-poly[[[aquabis(1h-imidazole-κn
(3))copper(ii)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ(2)
o:o′] dihydrate] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420079/ https://www.ncbi.nlm.nih.gov/pubmed/25995888 http://dx.doi.org/10.1107/S205698901500626X |
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