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Crystal structure of (E)-2-fluorobenzaldehyde (pyridin-2-yl)hydrazone
The title compound, C(12)H(10)FN(3), is approximately planar: the dihedral angles between the mean plane of the central N—N=C spacer unit and the fluorobenzene and pyridine rings are 14.50 (13) and 4.85 (15)°, respectively, while the dihedral angle between the aromatic rings is 16.29 (6)°. The F at...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420083/ https://www.ncbi.nlm.nih.gov/pubmed/25995950 http://dx.doi.org/10.1107/S2056989015007823 |
Sumario: | The title compound, C(12)H(10)FN(3), is approximately planar: the dihedral angles between the mean plane of the central N—N=C spacer unit and the fluorobenzene and pyridine rings are 14.50 (13) and 4.85 (15)°, respectively, while the dihedral angle between the aromatic rings is 16.29 (6)°. The F atom lies at the same side of the molecule as the N atom of the pyridine ring. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds generate R (2) (2)(8) loops. Molecules related by translation in the a direction are linked by two π–π stacking interactions involving pairs of benzene rings and pairs of pyridine rings. In each case, the ring-centroid separation is 3.8517 (9) Å. Two chains of this type pass through each unit cell, but there are no direction-specific interactions between adjacent chains. |
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