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Crystal structure of (E)-2-fluoro­benz­aldehyde (pyridin-2-yl)hydrazone

The title compound, C(12)H(10)FN(3), is approximately planar: the dihedral angles between the mean plane of the central N—N=C spacer unit and the fluoro­benzene and pyridine rings are 14.50 (13) and 4.85 (15)°, respectively, while the dihedral angle between the aromatic rings is 16.29 (6)°. The F at...

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Detalles Bibliográficos
Autores principales: Sowmya, Haliwana B. V., Suresha Kumara, Tholappanavara H., Jasinski, Jerry P., Millikan, Sean P., Glidewell, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420083/
https://www.ncbi.nlm.nih.gov/pubmed/25995950
http://dx.doi.org/10.1107/S2056989015007823
Descripción
Sumario:The title compound, C(12)H(10)FN(3), is approximately planar: the dihedral angles between the mean plane of the central N—N=C spacer unit and the fluoro­benzene and pyridine rings are 14.50 (13) and 4.85 (15)°, respectively, while the dihedral angle between the aromatic rings is 16.29 (6)°. The F atom lies at the same side of the mol­ecule as the N atom of the pyridine ring. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds generate R (2) (2)(8) loops. Mol­ecules related by translation in the a direction are linked by two π–π stacking inter­actions involving pairs of benzene rings and pairs of pyridine rings. In each case, the ring-centroid separation is 3.8517 (9) Å. Two chains of this type pass through each unit cell, but there are no direction-specific inter­actions between adjacent chains.