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Crystal structure of (E)-2-fluoro­benz­aldehyde (pyridin-2-yl)hydrazone

The title compound, C(12)H(10)FN(3), is approximately planar: the dihedral angles between the mean plane of the central N—N=C spacer unit and the fluoro­benzene and pyridine rings are 14.50 (13) and 4.85 (15)°, respectively, while the dihedral angle between the aromatic rings is 16.29 (6)°. The F at...

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Autores principales: Sowmya, Haliwana B. V., Suresha Kumara, Tholappanavara H., Jasinski, Jerry P., Millikan, Sean P., Glidewell, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420083/
https://www.ncbi.nlm.nih.gov/pubmed/25995950
http://dx.doi.org/10.1107/S2056989015007823
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author Sowmya, Haliwana B. V.
Suresha Kumara, Tholappanavara H.
Jasinski, Jerry P.
Millikan, Sean P.
Glidewell, Christopher
author_facet Sowmya, Haliwana B. V.
Suresha Kumara, Tholappanavara H.
Jasinski, Jerry P.
Millikan, Sean P.
Glidewell, Christopher
author_sort Sowmya, Haliwana B. V.
collection PubMed
description The title compound, C(12)H(10)FN(3), is approximately planar: the dihedral angles between the mean plane of the central N—N=C spacer unit and the fluoro­benzene and pyridine rings are 14.50 (13) and 4.85 (15)°, respectively, while the dihedral angle between the aromatic rings is 16.29 (6)°. The F atom lies at the same side of the mol­ecule as the N atom of the pyridine ring. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds generate R (2) (2)(8) loops. Mol­ecules related by translation in the a direction are linked by two π–π stacking inter­actions involving pairs of benzene rings and pairs of pyridine rings. In each case, the ring-centroid separation is 3.8517 (9) Å. Two chains of this type pass through each unit cell, but there are no direction-specific inter­actions between adjacent chains.
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spelling pubmed-44200832015-05-20 Crystal structure of (E)-2-fluoro­benz­aldehyde (pyridin-2-yl)hydrazone Sowmya, Haliwana B. V. Suresha Kumara, Tholappanavara H. Jasinski, Jerry P. Millikan, Sean P. Glidewell, Christopher Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(12)H(10)FN(3), is approximately planar: the dihedral angles between the mean plane of the central N—N=C spacer unit and the fluoro­benzene and pyridine rings are 14.50 (13) and 4.85 (15)°, respectively, while the dihedral angle between the aromatic rings is 16.29 (6)°. The F atom lies at the same side of the mol­ecule as the N atom of the pyridine ring. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds generate R (2) (2)(8) loops. Mol­ecules related by translation in the a direction are linked by two π–π stacking inter­actions involving pairs of benzene rings and pairs of pyridine rings. In each case, the ring-centroid separation is 3.8517 (9) Å. Two chains of this type pass through each unit cell, but there are no direction-specific inter­actions between adjacent chains. International Union of Crystallography 2015-04-30 /pmc/articles/PMC4420083/ /pubmed/25995950 http://dx.doi.org/10.1107/S2056989015007823 Text en © Sowmya et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Sowmya, Haliwana B. V.
Suresha Kumara, Tholappanavara H.
Jasinski, Jerry P.
Millikan, Sean P.
Glidewell, Christopher
Crystal structure of (E)-2-fluoro­benz­aldehyde (pyridin-2-yl)hydrazone
title Crystal structure of (E)-2-fluoro­benz­aldehyde (pyridin-2-yl)hydrazone
title_full Crystal structure of (E)-2-fluoro­benz­aldehyde (pyridin-2-yl)hydrazone
title_fullStr Crystal structure of (E)-2-fluoro­benz­aldehyde (pyridin-2-yl)hydrazone
title_full_unstemmed Crystal structure of (E)-2-fluoro­benz­aldehyde (pyridin-2-yl)hydrazone
title_short Crystal structure of (E)-2-fluoro­benz­aldehyde (pyridin-2-yl)hydrazone
title_sort crystal structure of (e)-2-fluoro­benz­aldehyde (pyridin-2-yl)hydrazone
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420083/
https://www.ncbi.nlm.nih.gov/pubmed/25995950
http://dx.doi.org/10.1107/S2056989015007823
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