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Crystal structure of (E)-2-fluorobenzaldehyde (pyridin-2-yl)hydrazone
The title compound, C(12)H(10)FN(3), is approximately planar: the dihedral angles between the mean plane of the central N—N=C spacer unit and the fluorobenzene and pyridine rings are 14.50 (13) and 4.85 (15)°, respectively, while the dihedral angle between the aromatic rings is 16.29 (6)°. The F at...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420083/ https://www.ncbi.nlm.nih.gov/pubmed/25995950 http://dx.doi.org/10.1107/S2056989015007823 |
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author | Sowmya, Haliwana B. V. Suresha Kumara, Tholappanavara H. Jasinski, Jerry P. Millikan, Sean P. Glidewell, Christopher |
author_facet | Sowmya, Haliwana B. V. Suresha Kumara, Tholappanavara H. Jasinski, Jerry P. Millikan, Sean P. Glidewell, Christopher |
author_sort | Sowmya, Haliwana B. V. |
collection | PubMed |
description | The title compound, C(12)H(10)FN(3), is approximately planar: the dihedral angles between the mean plane of the central N—N=C spacer unit and the fluorobenzene and pyridine rings are 14.50 (13) and 4.85 (15)°, respectively, while the dihedral angle between the aromatic rings is 16.29 (6)°. The F atom lies at the same side of the molecule as the N atom of the pyridine ring. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds generate R (2) (2)(8) loops. Molecules related by translation in the a direction are linked by two π–π stacking interactions involving pairs of benzene rings and pairs of pyridine rings. In each case, the ring-centroid separation is 3.8517 (9) Å. Two chains of this type pass through each unit cell, but there are no direction-specific interactions between adjacent chains. |
format | Online Article Text |
id | pubmed-4420083 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44200832015-05-20 Crystal structure of (E)-2-fluorobenzaldehyde (pyridin-2-yl)hydrazone Sowmya, Haliwana B. V. Suresha Kumara, Tholappanavara H. Jasinski, Jerry P. Millikan, Sean P. Glidewell, Christopher Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(12)H(10)FN(3), is approximately planar: the dihedral angles between the mean plane of the central N—N=C spacer unit and the fluorobenzene and pyridine rings are 14.50 (13) and 4.85 (15)°, respectively, while the dihedral angle between the aromatic rings is 16.29 (6)°. The F atom lies at the same side of the molecule as the N atom of the pyridine ring. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds generate R (2) (2)(8) loops. Molecules related by translation in the a direction are linked by two π–π stacking interactions involving pairs of benzene rings and pairs of pyridine rings. In each case, the ring-centroid separation is 3.8517 (9) Å. Two chains of this type pass through each unit cell, but there are no direction-specific interactions between adjacent chains. International Union of Crystallography 2015-04-30 /pmc/articles/PMC4420083/ /pubmed/25995950 http://dx.doi.org/10.1107/S2056989015007823 Text en © Sowmya et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Sowmya, Haliwana B. V. Suresha Kumara, Tholappanavara H. Jasinski, Jerry P. Millikan, Sean P. Glidewell, Christopher Crystal structure of (E)-2-fluorobenzaldehyde (pyridin-2-yl)hydrazone |
title | Crystal structure of (E)-2-fluorobenzaldehyde (pyridin-2-yl)hydrazone |
title_full | Crystal structure of (E)-2-fluorobenzaldehyde (pyridin-2-yl)hydrazone |
title_fullStr | Crystal structure of (E)-2-fluorobenzaldehyde (pyridin-2-yl)hydrazone |
title_full_unstemmed | Crystal structure of (E)-2-fluorobenzaldehyde (pyridin-2-yl)hydrazone |
title_short | Crystal structure of (E)-2-fluorobenzaldehyde (pyridin-2-yl)hydrazone |
title_sort | crystal structure of (e)-2-fluorobenzaldehyde (pyridin-2-yl)hydrazone |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420083/ https://www.ncbi.nlm.nih.gov/pubmed/25995950 http://dx.doi.org/10.1107/S2056989015007823 |
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