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Crystal structure of 2-methyl-N-[(4-methylpyridin-2-yl)carbamothioyl]benzamide
In the title compound, C(15)H(15)N(3)OS, there is an intramolecular N—H⋯O hydrogen bond and an intramolecular C—H⋯S hydrogen bond involving the C=O and C=S bonds which lie on opposite sides of the molecule. The molecule is non-planar with the benzene and pyridine rings being inclined to one anot...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420090/ https://www.ncbi.nlm.nih.gov/pubmed/25995946 http://dx.doi.org/10.1107/S2056989015007860 |
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author | Ameram, Nadiah Adam, Farook Fatihah, Nur Nadia Al-Juaid, Salih |
author_facet | Ameram, Nadiah Adam, Farook Fatihah, Nur Nadia Al-Juaid, Salih |
author_sort | Ameram, Nadiah |
collection | PubMed |
description | In the title compound, C(15)H(15)N(3)OS, there is an intramolecular N—H⋯O hydrogen bond and an intramolecular C—H⋯S hydrogen bond involving the C=O and C=S bonds which lie on opposite sides of the molecule. The molecule is non-planar with the benzene and pyridine rings being inclined to one another by 26.86 (9)°. In the crystal, molecules are linked by pairs of N—H⋯S hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. The dimers are linked via C—H⋯S hydrogen bonds, forming slabs parallel to the bc plane. |
format | Online Article Text |
id | pubmed-4420090 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44200902015-05-20 Crystal structure of 2-methyl-N-[(4-methylpyridin-2-yl)carbamothioyl]benzamide Ameram, Nadiah Adam, Farook Fatihah, Nur Nadia Al-Juaid, Salih Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(15)H(15)N(3)OS, there is an intramolecular N—H⋯O hydrogen bond and an intramolecular C—H⋯S hydrogen bond involving the C=O and C=S bonds which lie on opposite sides of the molecule. The molecule is non-planar with the benzene and pyridine rings being inclined to one another by 26.86 (9)°. In the crystal, molecules are linked by pairs of N—H⋯S hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. The dimers are linked via C—H⋯S hydrogen bonds, forming slabs parallel to the bc plane. International Union of Crystallography 2015-04-30 /pmc/articles/PMC4420090/ /pubmed/25995946 http://dx.doi.org/10.1107/S2056989015007860 Text en © Ameram et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Ameram, Nadiah Adam, Farook Fatihah, Nur Nadia Al-Juaid, Salih Crystal structure of 2-methyl-N-[(4-methylpyridin-2-yl)carbamothioyl]benzamide |
title | Crystal structure of 2-methyl-N-[(4-methylpyridin-2-yl)carbamothioyl]benzamide |
title_full | Crystal structure of 2-methyl-N-[(4-methylpyridin-2-yl)carbamothioyl]benzamide |
title_fullStr | Crystal structure of 2-methyl-N-[(4-methylpyridin-2-yl)carbamothioyl]benzamide |
title_full_unstemmed | Crystal structure of 2-methyl-N-[(4-methylpyridin-2-yl)carbamothioyl]benzamide |
title_short | Crystal structure of 2-methyl-N-[(4-methylpyridin-2-yl)carbamothioyl]benzamide |
title_sort | crystal structure of 2-methyl-n-[(4-methylpyridin-2-yl)carbamothioyl]benzamide |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420090/ https://www.ncbi.nlm.nih.gov/pubmed/25995946 http://dx.doi.org/10.1107/S2056989015007860 |
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