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Crystal structure of 2-methyl-N-[(4-methyl­pyridin-2-yl)carbamo­thio­yl]benzamide

In the title compound, C(15)H(15)N(3)OS, there is an intra­molecular N—H⋯O hydrogen bond and an intra­molecular C—H⋯S hydrogen bond involving the C=O and C=S bonds which lie on opposite sides of the mol­ecule. The mol­ecule is non-planar with the benzene and pyridine rings being inclined to one anot...

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Autores principales: Ameram, Nadiah, Adam, Farook, Fatihah, Nur Nadia, Al-Juaid, Salih
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420090/
https://www.ncbi.nlm.nih.gov/pubmed/25995946
http://dx.doi.org/10.1107/S2056989015007860
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author Ameram, Nadiah
Adam, Farook
Fatihah, Nur Nadia
Al-Juaid, Salih
author_facet Ameram, Nadiah
Adam, Farook
Fatihah, Nur Nadia
Al-Juaid, Salih
author_sort Ameram, Nadiah
collection PubMed
description In the title compound, C(15)H(15)N(3)OS, there is an intra­molecular N—H⋯O hydrogen bond and an intra­molecular C—H⋯S hydrogen bond involving the C=O and C=S bonds which lie on opposite sides of the mol­ecule. The mol­ecule is non-planar with the benzene and pyridine rings being inclined to one another by 26.86 (9)°. In the crystal, mol­ecules are linked by pairs of N—H⋯S hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. The dimers are linked via C—H⋯S hydrogen bonds, forming slabs parallel to the bc plane.
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spelling pubmed-44200902015-05-20 Crystal structure of 2-methyl-N-[(4-methyl­pyridin-2-yl)carbamo­thio­yl]benzamide Ameram, Nadiah Adam, Farook Fatihah, Nur Nadia Al-Juaid, Salih Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(15)H(15)N(3)OS, there is an intra­molecular N—H⋯O hydrogen bond and an intra­molecular C—H⋯S hydrogen bond involving the C=O and C=S bonds which lie on opposite sides of the mol­ecule. The mol­ecule is non-planar with the benzene and pyridine rings being inclined to one another by 26.86 (9)°. In the crystal, mol­ecules are linked by pairs of N—H⋯S hydrogen bonds, forming inversion dimers with an R (2) (2)(8) ring motif. The dimers are linked via C—H⋯S hydrogen bonds, forming slabs parallel to the bc plane. International Union of Crystallography 2015-04-30 /pmc/articles/PMC4420090/ /pubmed/25995946 http://dx.doi.org/10.1107/S2056989015007860 Text en © Ameram et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ameram, Nadiah
Adam, Farook
Fatihah, Nur Nadia
Al-Juaid, Salih
Crystal structure of 2-methyl-N-[(4-methyl­pyridin-2-yl)carbamo­thio­yl]benzamide
title Crystal structure of 2-methyl-N-[(4-methyl­pyridin-2-yl)carbamo­thio­yl]benzamide
title_full Crystal structure of 2-methyl-N-[(4-methyl­pyridin-2-yl)carbamo­thio­yl]benzamide
title_fullStr Crystal structure of 2-methyl-N-[(4-methyl­pyridin-2-yl)carbamo­thio­yl]benzamide
title_full_unstemmed Crystal structure of 2-methyl-N-[(4-methyl­pyridin-2-yl)carbamo­thio­yl]benzamide
title_short Crystal structure of 2-methyl-N-[(4-methyl­pyridin-2-yl)carbamo­thio­yl]benzamide
title_sort crystal structure of 2-methyl-n-[(4-methyl­pyridin-2-yl)carbamo­thio­yl]benzamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420090/
https://www.ncbi.nlm.nih.gov/pubmed/25995946
http://dx.doi.org/10.1107/S2056989015007860
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