Crystal structure of bis­[4-(di­methyl­amino)­pyridine-κN (1)]bis­(methanol-κO)bis­(thio­cyanato-κN)manganese(II)

The whole mol­ecule of the title compound, [Mn(NCS)(2)(CH(3)OH)(2)(C(5)H(6)N(2))(2)], is generated by inversion symmetry. The Mn(II) ion, which is located on an inversion center, is coordinated by two 4-(di­methyl­amino)­pyridine ligands, two methanol ligands and two terminally N-bonded thio­cyanate...

Descripción completa

Detalles Bibliográficos
Autores principales: Suckert, Stefan, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420091/
https://www.ncbi.nlm.nih.gov/pubmed/25995897
http://dx.doi.org/10.1107/S2056989015007318
Descripción
Sumario:The whole mol­ecule of the title compound, [Mn(NCS)(2)(CH(3)OH)(2)(C(5)H(6)N(2))(2)], is generated by inversion symmetry. The Mn(II) ion, which is located on an inversion center, is coordinated by two 4-(di­methyl­amino)­pyridine ligands, two methanol ligands and two terminally N-bonded thio­cyanate anions, forming a slightly distorted octa­hedron. In the crystal, mol­ecules are linked by O—H⋯S hydrogen bonds, forming chains extending along the a-axis direction.

Ejemplares similares