Crystal structure of bis­[4-(di­methyl­amino)­pyridine-κN (1)]bis­(methanol-κO)bis­(thio­cyanato-κN)manganese(II)

The whole mol­ecule of the title compound, [Mn(NCS)(2)(CH(3)OH)(2)(C(5)H(6)N(2))(2)], is generated by inversion symmetry. The Mn(II) ion, which is located on an inversion center, is coordinated by two 4-(di­methyl­amino)­pyridine ligands, two methanol ligands and two terminally N-bonded thio­cyanate...

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Detalles Bibliográficos
Autores principales: Suckert, Stefan, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420091/
https://www.ncbi.nlm.nih.gov/pubmed/25995897
http://dx.doi.org/10.1107/S2056989015007318
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author Suckert, Stefan
Jess, Inke
Näther, Christian
author_facet Suckert, Stefan
Jess, Inke
Näther, Christian
author_sort Suckert, Stefan
collection PubMed
description The whole mol­ecule of the title compound, [Mn(NCS)(2)(CH(3)OH)(2)(C(5)H(6)N(2))(2)], is generated by inversion symmetry. The Mn(II) ion, which is located on an inversion center, is coordinated by two 4-(di­methyl­amino)­pyridine ligands, two methanol ligands and two terminally N-bonded thio­cyanate anions, forming a slightly distorted octa­hedron. In the crystal, mol­ecules are linked by O—H⋯S hydrogen bonds, forming chains extending along the a-axis direction.
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spelling pubmed-44200912015-05-20 Crystal structure of bis­[4-(di­methyl­amino)­pyridine-κN (1)]bis­(methanol-κO)bis­(thio­cyanato-κN)manganese(II) Suckert, Stefan Jess, Inke Näther, Christian Acta Crystallogr E Crystallogr Commun Data Reports The whole mol­ecule of the title compound, [Mn(NCS)(2)(CH(3)OH)(2)(C(5)H(6)N(2))(2)], is generated by inversion symmetry. The Mn(II) ion, which is located on an inversion center, is coordinated by two 4-(di­methyl­amino)­pyridine ligands, two methanol ligands and two terminally N-bonded thio­cyanate anions, forming a slightly distorted octa­hedron. In the crystal, mol­ecules are linked by O—H⋯S hydrogen bonds, forming chains extending along the a-axis direction. International Union of Crystallography 2015-04-30 /pmc/articles/PMC4420091/ /pubmed/25995897 http://dx.doi.org/10.1107/S2056989015007318 Text en © Suckert et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Suckert, Stefan
Jess, Inke
Näther, Christian
Crystal structure of bis­[4-(di­methyl­amino)­pyridine-κN (1)]bis­(methanol-κO)bis­(thio­cyanato-κN)manganese(II)
title Crystal structure of bis­[4-(di­methyl­amino)­pyridine-κN (1)]bis­(methanol-κO)bis­(thio­cyanato-κN)manganese(II)
title_full Crystal structure of bis­[4-(di­methyl­amino)­pyridine-κN (1)]bis­(methanol-κO)bis­(thio­cyanato-κN)manganese(II)
title_fullStr Crystal structure of bis­[4-(di­methyl­amino)­pyridine-κN (1)]bis­(methanol-κO)bis­(thio­cyanato-κN)manganese(II)
title_full_unstemmed Crystal structure of bis­[4-(di­methyl­amino)­pyridine-κN (1)]bis­(methanol-κO)bis­(thio­cyanato-κN)manganese(II)
title_short Crystal structure of bis­[4-(di­methyl­amino)­pyridine-κN (1)]bis­(methanol-κO)bis­(thio­cyanato-κN)manganese(II)
title_sort crystal structure of bis­[4-(di­methyl­amino)­pyridine-κn (1)]bis­(methanol-κo)bis­(thio­cyanato-κn)manganese(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420091/
https://www.ncbi.nlm.nih.gov/pubmed/25995897
http://dx.doi.org/10.1107/S2056989015007318
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