Crystal structure of 3-bromo­methyl-2-chloro-6-(di­bromo­meth­yl)quinoline

In the title compound, C(11)H(7)Br(3)ClN, the quinoline ring system is approximately planar (r.m.s. = 0.011 Å). In the crystal, mol­ecules are linked by C—H⋯Br inter­actions forming chains along [10-1]. The chains are linked by C—H⋯π and π–π inter­actions involving inversion-related pyridine rings [...

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Detalles Bibliográficos
Autores principales: Gayathri, Kasirajan, Mohan, Palathurai S., Howard, Judith A. K., Sparkes, Hazel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420095/
https://www.ncbi.nlm.nih.gov/pubmed/25995945
http://dx.doi.org/10.1107/S2056989015008002
Descripción
Sumario:In the title compound, C(11)H(7)Br(3)ClN, the quinoline ring system is approximately planar (r.m.s. = 0.011 Å). In the crystal, mol­ecules are linked by C—H⋯Br inter­actions forming chains along [10-1]. The chains are linked by C—H⋯π and π–π inter­actions involving inversion-related pyridine rings [inter­centroid distance = 3.608 (4) Å], forming sheets parallel to (10-1). Within the sheets, there are two significant short inter­actions involving a Br⋯Cl contact of 3.4904 (18) Å and a Br⋯N contact of 3.187 (6) Å, both of which are significantly shorter than the sum of their van der Waals radii.

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