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Crystal structure of methyl 1-methyl-2-oxo­spiro­[indoline-3,2′-oxirane]-3′-carboxyl­ate

In the title compound, C(12)H(11)NO(4), the dihedral angle between the indole ring system (r.m.s. deviation = 0.019 Å) and the oxirane ring is 88.8 (2)°. The oxirane O atom and the bridging ester O atom are in an approximate syn conformation [O—C—C—O = −25.4 (3)°] In the crystal, inversion dimers li...

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Autores principales: Savithri, M. P., Yuvaraj, P. S., Reddy, B. S. R., Raja, R., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420098/
https://www.ncbi.nlm.nih.gov/pubmed/25995901
http://dx.doi.org/10.1107/S2056989015006398
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author Savithri, M. P.
Yuvaraj, P. S.
Reddy, B. S. R.
Raja, R.
SubbiahPandi, A.
author_facet Savithri, M. P.
Yuvaraj, P. S.
Reddy, B. S. R.
Raja, R.
SubbiahPandi, A.
author_sort Savithri, M. P.
collection PubMed
description In the title compound, C(12)H(11)NO(4), the dihedral angle between the indole ring system (r.m.s. deviation = 0.019 Å) and the oxirane ring is 88.8 (2)°. The oxirane O atom and the bridging ester O atom are in an approximate syn conformation [O—C—C—O = −25.4 (3)°] In the crystal, inversion dimers linked by pair of C—H⋯O hydrogen bonds generate R (2) (2)(8) loops, where the C—H donor group forms part of the oxirane ring. A second C—H⋯O inter­action arising from one of the C—H groups of the benzene ring links the dimers into [001] double chains.
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spelling pubmed-44200982015-05-20 Crystal structure of methyl 1-methyl-2-oxo­spiro­[indoline-3,2′-oxirane]-3′-carboxyl­ate Savithri, M. P. Yuvaraj, P. S. Reddy, B. S. R. Raja, R. SubbiahPandi, A. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(12)H(11)NO(4), the dihedral angle between the indole ring system (r.m.s. deviation = 0.019 Å) and the oxirane ring is 88.8 (2)°. The oxirane O atom and the bridging ester O atom are in an approximate syn conformation [O—C—C—O = −25.4 (3)°] In the crystal, inversion dimers linked by pair of C—H⋯O hydrogen bonds generate R (2) (2)(8) loops, where the C—H donor group forms part of the oxirane ring. A second C—H⋯O inter­action arising from one of the C—H groups of the benzene ring links the dimers into [001] double chains. International Union of Crystallography 2015-04-02 /pmc/articles/PMC4420098/ /pubmed/25995901 http://dx.doi.org/10.1107/S2056989015006398 Text en © Savithri et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Savithri, M. P.
Yuvaraj, P. S.
Reddy, B. S. R.
Raja, R.
SubbiahPandi, A.
Crystal structure of methyl 1-methyl-2-oxo­spiro­[indoline-3,2′-oxirane]-3′-carboxyl­ate
title Crystal structure of methyl 1-methyl-2-oxo­spiro­[indoline-3,2′-oxirane]-3′-carboxyl­ate
title_full Crystal structure of methyl 1-methyl-2-oxo­spiro­[indoline-3,2′-oxirane]-3′-carboxyl­ate
title_fullStr Crystal structure of methyl 1-methyl-2-oxo­spiro­[indoline-3,2′-oxirane]-3′-carboxyl­ate
title_full_unstemmed Crystal structure of methyl 1-methyl-2-oxo­spiro­[indoline-3,2′-oxirane]-3′-carboxyl­ate
title_short Crystal structure of methyl 1-methyl-2-oxo­spiro­[indoline-3,2′-oxirane]-3′-carboxyl­ate
title_sort crystal structure of methyl 1-methyl-2-oxo­spiro­[indoline-3,2′-oxirane]-3′-carboxyl­ate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420098/
https://www.ncbi.nlm.nih.gov/pubmed/25995901
http://dx.doi.org/10.1107/S2056989015006398
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