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Crystal structure of bis(2-amino-5-chloropyridinium) tetrachloridocobaltate(II)
The title salt, (C(5)H(6)ClN(2))(2)[CoCl(4)], was synthesized by slow evaporation of an aqueous solution at room temperature. The asymmetric unit consists of two essentially planar (C(5)H(6)ClN(2))(+) cations [maximum deviations = 0.010 (3) and 0.014 (3) Å] that are nearly perpendicular to each othe...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420110/ https://www.ncbi.nlm.nih.gov/pubmed/25995878 http://dx.doi.org/10.1107/S2056989015007707 |
| Sumario: | The title salt, (C(5)H(6)ClN(2))(2)[CoCl(4)], was synthesized by slow evaporation of an aqueous solution at room temperature. The asymmetric unit consists of two essentially planar (C(5)H(6)ClN(2))(+) cations [maximum deviations = 0.010 (3) and 0.014 (3) Å] that are nearly perpendicular to each other [dihedral angle = 84.12 (7)°]. They are bonded through N—H⋯Cl hydrogen bonds to distorted [CoCl(4)](2−) tetrahedra, leading to the formation of undulating layers parallel to (100). The structure is isotypic with the Zn analogue [Kefi et. al (2011). Acta Cryst. E67, m355–m356.] |
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