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Crystal structure of 2-methyl-1H-imidazol-3-ium aquatrichlorido(oxalato-κ(2) O,O′)stannate(IV)
The tin(IV) atom in the complex anion of the title salt, (C(4)H(7)N(2))[Sn(C(2)O(4))Cl(3)(H(2)O)], is in a distorted octahedral coordination environment defined by three chlorido ligands, an oxygen atom from a water molecule and two oxygen atoms from a chelating oxalate anion. The organic cation i...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420124/ https://www.ncbi.nlm.nih.gov/pubmed/25995870 http://dx.doi.org/10.1107/S2056989015005988 |
Sumario: | The tin(IV) atom in the complex anion of the title salt, (C(4)H(7)N(2))[Sn(C(2)O(4))Cl(3)(H(2)O)], is in a distorted octahedral coordination environment defined by three chlorido ligands, an oxygen atom from a water molecule and two oxygen atoms from a chelating oxalate anion. The organic cation is linked through a bifurcated N—H⋯O hydrogen bond to the free oxygen atoms of the oxalate ligand of the complex [Sn(H(2)O)Cl(3)(C(2)O(4))](−) anion. Neighbouring stannate(IV) anions are linked through O—H⋯O hydrogen bonds involving the water molecule and the two non-coordinating oxalate oxygen atoms. In combination with additional N—H⋯Cl hydrogen bonds between cations and anions, a three-dimensional network is spanned. |
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