Cargando…
Crystal structure of 2-methyl-1H-imidazol-3-ium aquatrichlorido(oxalato-κ(2) O,O′)stannate(IV)
The tin(IV) atom in the complex anion of the title salt, (C(4)H(7)N(2))[Sn(C(2)O(4))Cl(3)(H(2)O)], is in a distorted octahedral coordination environment defined by three chlorido ligands, an oxygen atom from a water molecule and two oxygen atoms from a chelating oxalate anion. The organic cation i...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420124/ https://www.ncbi.nlm.nih.gov/pubmed/25995870 http://dx.doi.org/10.1107/S2056989015005988 |
_version_ | 1782369675582111744 |
---|---|
author | Diop, Mouhamadou Birame Diop, Libasse Plasseraud, Laurent Maris, Thierry |
author_facet | Diop, Mouhamadou Birame Diop, Libasse Plasseraud, Laurent Maris, Thierry |
author_sort | Diop, Mouhamadou Birame |
collection | PubMed |
description | The tin(IV) atom in the complex anion of the title salt, (C(4)H(7)N(2))[Sn(C(2)O(4))Cl(3)(H(2)O)], is in a distorted octahedral coordination environment defined by three chlorido ligands, an oxygen atom from a water molecule and two oxygen atoms from a chelating oxalate anion. The organic cation is linked through a bifurcated N—H⋯O hydrogen bond to the free oxygen atoms of the oxalate ligand of the complex [Sn(H(2)O)Cl(3)(C(2)O(4))](−) anion. Neighbouring stannate(IV) anions are linked through O—H⋯O hydrogen bonds involving the water molecule and the two non-coordinating oxalate oxygen atoms. In combination with additional N—H⋯Cl hydrogen bonds between cations and anions, a three-dimensional network is spanned. |
format | Online Article Text |
id | pubmed-4420124 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-44201242015-05-20 Crystal structure of 2-methyl-1H-imidazol-3-ium aquatrichlorido(oxalato-κ(2) O,O′)stannate(IV) Diop, Mouhamadou Birame Diop, Libasse Plasseraud, Laurent Maris, Thierry Acta Crystallogr E Crystallogr Commun Research Communications The tin(IV) atom in the complex anion of the title salt, (C(4)H(7)N(2))[Sn(C(2)O(4))Cl(3)(H(2)O)], is in a distorted octahedral coordination environment defined by three chlorido ligands, an oxygen atom from a water molecule and two oxygen atoms from a chelating oxalate anion. The organic cation is linked through a bifurcated N—H⋯O hydrogen bond to the free oxygen atoms of the oxalate ligand of the complex [Sn(H(2)O)Cl(3)(C(2)O(4))](−) anion. Neighbouring stannate(IV) anions are linked through O—H⋯O hydrogen bonds involving the water molecule and the two non-coordinating oxalate oxygen atoms. In combination with additional N—H⋯Cl hydrogen bonds between cations and anions, a three-dimensional network is spanned. International Union of Crystallography 2015-04-22 /pmc/articles/PMC4420124/ /pubmed/25995870 http://dx.doi.org/10.1107/S2056989015005988 Text en © Diop et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Diop, Mouhamadou Birame Diop, Libasse Plasseraud, Laurent Maris, Thierry Crystal structure of 2-methyl-1H-imidazol-3-ium aquatrichlorido(oxalato-κ(2) O,O′)stannate(IV) |
title | Crystal structure of 2-methyl-1H-imidazol-3-ium aquatrichlorido(oxalato-κ(2)
O,O′)stannate(IV) |
title_full | Crystal structure of 2-methyl-1H-imidazol-3-ium aquatrichlorido(oxalato-κ(2)
O,O′)stannate(IV) |
title_fullStr | Crystal structure of 2-methyl-1H-imidazol-3-ium aquatrichlorido(oxalato-κ(2)
O,O′)stannate(IV) |
title_full_unstemmed | Crystal structure of 2-methyl-1H-imidazol-3-ium aquatrichlorido(oxalato-κ(2)
O,O′)stannate(IV) |
title_short | Crystal structure of 2-methyl-1H-imidazol-3-ium aquatrichlorido(oxalato-κ(2)
O,O′)stannate(IV) |
title_sort | crystal structure of 2-methyl-1h-imidazol-3-ium aquatrichlorido(oxalato-κ(2)
o,o′)stannate(iv) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420124/ https://www.ncbi.nlm.nih.gov/pubmed/25995870 http://dx.doi.org/10.1107/S2056989015005988 |
work_keys_str_mv | AT diopmouhamadoubirame crystalstructureof2methyl1himidazol3iumaquatrichloridooxalatok2oostannateiv AT dioplibasse crystalstructureof2methyl1himidazol3iumaquatrichloridooxalatok2oostannateiv AT plasseraudlaurent crystalstructureof2methyl1himidazol3iumaquatrichloridooxalatok2oostannateiv AT maristhierry crystalstructureof2methyl1himidazol3iumaquatrichloridooxalatok2oostannateiv |