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Crystal structure of 2-methyl-1H-imidazol-3-ium aqua­tri­chlorido­(oxalato-κ(2) O,O′)stannate(IV)

The tin(IV) atom in the complex anion of the title salt, (C(4)H(7)N(2))[Sn(C(2)O(4))Cl(3)(H(2)O)], is in a distorted octa­hedral coordination environment defined by three chlorido ligands, an oxygen atom from a water mol­ecule and two oxygen atoms from a chelating oxalate anion. The organic cation i...

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Autores principales: Diop, Mouhamadou Birame, Diop, Libasse, Plasseraud, Laurent, Maris, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420124/
https://www.ncbi.nlm.nih.gov/pubmed/25995870
http://dx.doi.org/10.1107/S2056989015005988
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author Diop, Mouhamadou Birame
Diop, Libasse
Plasseraud, Laurent
Maris, Thierry
author_facet Diop, Mouhamadou Birame
Diop, Libasse
Plasseraud, Laurent
Maris, Thierry
author_sort Diop, Mouhamadou Birame
collection PubMed
description The tin(IV) atom in the complex anion of the title salt, (C(4)H(7)N(2))[Sn(C(2)O(4))Cl(3)(H(2)O)], is in a distorted octa­hedral coordination environment defined by three chlorido ligands, an oxygen atom from a water mol­ecule and two oxygen atoms from a chelating oxalate anion. The organic cation is linked through a bifurcated N—H⋯O hydrogen bond to the free oxygen atoms of the oxalate ligand of the complex [Sn(H(2)O)Cl(3)(C(2)O(4))](−) anion. Neighbouring stannate(IV) anions are linked through O—H⋯O hydrogen bonds involving the water mol­ecule and the two non-coordinating oxalate oxygen atoms. In combination with additional N—H⋯Cl hydrogen bonds between cations and anions, a three-dimensional network is spanned.
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spelling pubmed-44201242015-05-20 Crystal structure of 2-methyl-1H-imidazol-3-ium aqua­tri­chlorido­(oxalato-κ(2) O,O′)stannate(IV) Diop, Mouhamadou Birame Diop, Libasse Plasseraud, Laurent Maris, Thierry Acta Crystallogr E Crystallogr Commun Research Communications The tin(IV) atom in the complex anion of the title salt, (C(4)H(7)N(2))[Sn(C(2)O(4))Cl(3)(H(2)O)], is in a distorted octa­hedral coordination environment defined by three chlorido ligands, an oxygen atom from a water mol­ecule and two oxygen atoms from a chelating oxalate anion. The organic cation is linked through a bifurcated N—H⋯O hydrogen bond to the free oxygen atoms of the oxalate ligand of the complex [Sn(H(2)O)Cl(3)(C(2)O(4))](−) anion. Neighbouring stannate(IV) anions are linked through O—H⋯O hydrogen bonds involving the water mol­ecule and the two non-coordinating oxalate oxygen atoms. In combination with additional N—H⋯Cl hydrogen bonds between cations and anions, a three-dimensional network is spanned. International Union of Crystallography 2015-04-22 /pmc/articles/PMC4420124/ /pubmed/25995870 http://dx.doi.org/10.1107/S2056989015005988 Text en © Diop et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Diop, Mouhamadou Birame
Diop, Libasse
Plasseraud, Laurent
Maris, Thierry
Crystal structure of 2-methyl-1H-imidazol-3-ium aqua­tri­chlorido­(oxalato-κ(2) O,O′)stannate(IV)
title Crystal structure of 2-methyl-1H-imidazol-3-ium aqua­tri­chlorido­(oxalato-κ(2) O,O′)stannate(IV)
title_full Crystal structure of 2-methyl-1H-imidazol-3-ium aqua­tri­chlorido­(oxalato-κ(2) O,O′)stannate(IV)
title_fullStr Crystal structure of 2-methyl-1H-imidazol-3-ium aqua­tri­chlorido­(oxalato-κ(2) O,O′)stannate(IV)
title_full_unstemmed Crystal structure of 2-methyl-1H-imidazol-3-ium aqua­tri­chlorido­(oxalato-κ(2) O,O′)stannate(IV)
title_short Crystal structure of 2-methyl-1H-imidazol-3-ium aqua­tri­chlorido­(oxalato-κ(2) O,O′)stannate(IV)
title_sort crystal structure of 2-methyl-1h-imidazol-3-ium aqua­tri­chlorido­(oxalato-κ(2) o,o′)stannate(iv)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420124/
https://www.ncbi.nlm.nih.gov/pubmed/25995870
http://dx.doi.org/10.1107/S2056989015005988
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