Crystal structure of (E)-2-({[2-(1,3-dioxan-2-yl)phen­yl]imino}­meth­yl)phenol

The title compound, C(17)H(17)NO(3), prepared by the condensation reaction of 2-(1,3-dioxan-2-yl)aniline and salicyl­aldehyde, has an E conformation about the C=N bond. The six-membered O-heterocycle adopts a chair conformation, with the bond to the aromatic ring located at its equatorial position....

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Detalles Bibliográficos
Autores principales: Li, Zhengyi, Shi, Song, Zhou, Kun, Chen, Liang, Sun, Xiaoqiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420126/
https://www.ncbi.nlm.nih.gov/pubmed/25995947
http://dx.doi.org/10.1107/S2056989015008051
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author Li, Zhengyi
Shi, Song
Zhou, Kun
Chen, Liang
Sun, Xiaoqiang
author_facet Li, Zhengyi
Shi, Song
Zhou, Kun
Chen, Liang
Sun, Xiaoqiang
author_sort Li, Zhengyi
collection PubMed
description The title compound, C(17)H(17)NO(3), prepared by the condensation reaction of 2-(1,3-dioxan-2-yl)aniline and salicyl­aldehyde, has an E conformation about the C=N bond. The six-membered O-heterocycle adopts a chair conformation, with the bond to the aromatic ring located at its equatorial position. The dihedral angle between the aromatic rings is 36.54 (9)°. There is an intra­molecular N—H⋯O hydrogen bond forming an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming chains along the a-axis direction. Within the chains, there are C—H⋯π inter­actions involving adjacent mol­ecules.
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spelling pubmed-44201262015-05-20 Crystal structure of (E)-2-({[2-(1,3-dioxan-2-yl)phen­yl]imino}­meth­yl)phenol Li, Zhengyi Shi, Song Zhou, Kun Chen, Liang Sun, Xiaoqiang Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(17)H(17)NO(3), prepared by the condensation reaction of 2-(1,3-dioxan-2-yl)aniline and salicyl­aldehyde, has an E conformation about the C=N bond. The six-membered O-heterocycle adopts a chair conformation, with the bond to the aromatic ring located at its equatorial position. The dihedral angle between the aromatic rings is 36.54 (9)°. There is an intra­molecular N—H⋯O hydrogen bond forming an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming chains along the a-axis direction. Within the chains, there are C—H⋯π inter­actions involving adjacent mol­ecules. International Union of Crystallography 2015-04-30 /pmc/articles/PMC4420126/ /pubmed/25995947 http://dx.doi.org/10.1107/S2056989015008051 Text en © Li et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Li, Zhengyi
Shi, Song
Zhou, Kun
Chen, Liang
Sun, Xiaoqiang
Crystal structure of (E)-2-({[2-(1,3-dioxan-2-yl)phen­yl]imino}­meth­yl)phenol
title Crystal structure of (E)-2-({[2-(1,3-dioxan-2-yl)phen­yl]imino}­meth­yl)phenol
title_full Crystal structure of (E)-2-({[2-(1,3-dioxan-2-yl)phen­yl]imino}­meth­yl)phenol
title_fullStr Crystal structure of (E)-2-({[2-(1,3-dioxan-2-yl)phen­yl]imino}­meth­yl)phenol
title_full_unstemmed Crystal structure of (E)-2-({[2-(1,3-dioxan-2-yl)phen­yl]imino}­meth­yl)phenol
title_short Crystal structure of (E)-2-({[2-(1,3-dioxan-2-yl)phen­yl]imino}­meth­yl)phenol
title_sort crystal structure of (e)-2-({[2-(1,3-dioxan-2-yl)phen­yl]imino}­meth­yl)phenol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420126/
https://www.ncbi.nlm.nih.gov/pubmed/25995947
http://dx.doi.org/10.1107/S2056989015008051
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AT chenliang crystalstructureofe2213dioxan2ylphenyliminomethylphenol
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