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Crystal structure of catena-poly[bis[μ(3)-2-(2-nitrophenyl)acetato-κ(3) O:O:O′]disilver(I)]
The title compound, [Ag(2)(C(8)H(6)NO(4))(2)](n), is a silver complex of 2-(2-nitrophenyl)acetic acid. The molecules are not conventional crystallographic inversion dimers but consist of two independent ligands and two Ag(I) ions, each with a distorted T-shaped coordination environment. The dihed...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420127/ https://www.ncbi.nlm.nih.gov/pubmed/25995893 http://dx.doi.org/10.1107/S2056989015007616 |
Sumario: | The title compound, [Ag(2)(C(8)H(6)NO(4))(2)](n), is a silver complex of 2-(2-nitrophenyl)acetic acid. The molecules are not conventional crystallographic inversion dimers but consist of two independent ligands and two Ag(I) ions, each with a distorted T-shaped coordination environment. The dihedral angles between acetate groups and the benzene rings are 51.1 (2) and 57.9 (2)°. The nitro groups are oriented at dihedral angles of 23.6 (5) and 32.3 (3)° with respect to the parent benzene rings. The dimers form polymeric chains along the a-axis direction. The Ag⋯Ag separation within a dimer is 2.8200 (5) and between symmetry-related dimers is 3.6182 (5) Å. The polymeric chains are interlinked by C—H⋯O hydrogen-bond interactions. |
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