Crystal structure of catena-poly[bis­[μ(3)-2-(2-nitro­phen­yl)acetato-κ(3) O:O:O′]disilver(I)]

The title compound, [Ag(2)(C(8)H(6)NO(4))(2)](n), is a silver complex of 2-(2-nitro­phen­yl)acetic acid. The mol­ecules are not conventional crystallographic inversion dimers but consist of two independent ligands and two Ag(I) ions, each with a distorted T-shaped coordination environment. The dihed...

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Autores principales: Danish, Muhammad, Tahir, Muhammad Nawaz, Iftikhar, Sana, Ahmad, Nazir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420127/
https://www.ncbi.nlm.nih.gov/pubmed/25995893
http://dx.doi.org/10.1107/S2056989015007616
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author Danish, Muhammad
Tahir, Muhammad Nawaz
Iftikhar, Sana
Ahmad, Nazir
author_facet Danish, Muhammad
Tahir, Muhammad Nawaz
Iftikhar, Sana
Ahmad, Nazir
author_sort Danish, Muhammad
collection PubMed
description The title compound, [Ag(2)(C(8)H(6)NO(4))(2)](n), is a silver complex of 2-(2-nitro­phen­yl)acetic acid. The mol­ecules are not conventional crystallographic inversion dimers but consist of two independent ligands and two Ag(I) ions, each with a distorted T-shaped coordination environment. The dihedral angles between acetate groups and the benzene rings are 51.1 (2) and 57.9 (2)°. The nitro groups are oriented at dihedral angles of 23.6 (5) and 32.3 (3)° with respect to the parent benzene rings. The dimers form polymeric chains along the a-axis direction. The Ag⋯Ag separation within a dimer is 2.8200 (5) and between symmetry-related dimers is 3.6182 (5) Å. The polymeric chains are inter­linked by C—H⋯O hydrogen-bond inter­actions.
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spelling pubmed-44201272015-05-20 Crystal structure of catena-poly[bis­[μ(3)-2-(2-nitro­phen­yl)acetato-κ(3) O:O:O′]disilver(I)] Danish, Muhammad Tahir, Muhammad Nawaz Iftikhar, Sana Ahmad, Nazir Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [Ag(2)(C(8)H(6)NO(4))(2)](n), is a silver complex of 2-(2-nitro­phen­yl)acetic acid. The mol­ecules are not conventional crystallographic inversion dimers but consist of two independent ligands and two Ag(I) ions, each with a distorted T-shaped coordination environment. The dihedral angles between acetate groups and the benzene rings are 51.1 (2) and 57.9 (2)°. The nitro groups are oriented at dihedral angles of 23.6 (5) and 32.3 (3)° with respect to the parent benzene rings. The dimers form polymeric chains along the a-axis direction. The Ag⋯Ag separation within a dimer is 2.8200 (5) and between symmetry-related dimers is 3.6182 (5) Å. The polymeric chains are inter­linked by C—H⋯O hydrogen-bond inter­actions. International Union of Crystallography 2015-04-25 /pmc/articles/PMC4420127/ /pubmed/25995893 http://dx.doi.org/10.1107/S2056989015007616 Text en © Danish et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Danish, Muhammad
Tahir, Muhammad Nawaz
Iftikhar, Sana
Ahmad, Nazir
Crystal structure of catena-poly[bis­[μ(3)-2-(2-nitro­phen­yl)acetato-κ(3) O:O:O′]disilver(I)]
title Crystal structure of catena-poly[bis­[μ(3)-2-(2-nitro­phen­yl)acetato-κ(3) O:O:O′]disilver(I)]
title_full Crystal structure of catena-poly[bis­[μ(3)-2-(2-nitro­phen­yl)acetato-κ(3) O:O:O′]disilver(I)]
title_fullStr Crystal structure of catena-poly[bis­[μ(3)-2-(2-nitro­phen­yl)acetato-κ(3) O:O:O′]disilver(I)]
title_full_unstemmed Crystal structure of catena-poly[bis­[μ(3)-2-(2-nitro­phen­yl)acetato-κ(3) O:O:O′]disilver(I)]
title_short Crystal structure of catena-poly[bis­[μ(3)-2-(2-nitro­phen­yl)acetato-κ(3) O:O:O′]disilver(I)]
title_sort crystal structure of catena-poly[bis­[μ(3)-2-(2-nitro­phen­yl)acetato-κ(3) o:o:o′]disilver(i)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420127/
https://www.ncbi.nlm.nih.gov/pubmed/25995893
http://dx.doi.org/10.1107/S2056989015007616
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