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Crystal structure of ({4-[(4-bromophenyl)ethynyl]-3,5-diethylphenyl}ethynyl)triisopropylsilane
The title compound, C(29)H(37)BrSi, was synthesized by the Sonogashira coupling of [(3,5-diethyl-4-ethynylphenyl)ethynyl]triisopropylsilane with 4-bromo-1-iodobenzene. In the structure, the two phenyl rings are nearly parallel to each other with a dihedral angle of 4.27 (4)°. In the crystal, π–...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420139/ https://www.ncbi.nlm.nih.gov/pubmed/25995927 http://dx.doi.org/10.1107/S2056989015007252 |
Sumario: | The title compound, C(29)H(37)BrSi, was synthesized by the Sonogashira coupling of [(3,5-diethyl-4-ethynylphenyl)ethynyl]triisopropylsilane with 4-bromo-1-iodobenzene. In the structure, the two phenyl rings are nearly parallel to each other with a dihedral angle of 4.27 (4)°. In the crystal, π–π interactions between the terminal and central phenyl rings of adjacent molecules link them in the a-axis direction [perpendicular distance = 3.5135 (14); centroid–centroid distance = 3.7393 (11) Å]. In addition, there are weak C—H⋯π interactions between the isopropyl H atoms and the phenyl rings of adjacent molecules. |
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